The effect of the nature of the stationary phase on the gas chromatographic retention of sorbates in monolithic columns View Full Text


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Article Info

DATE

2009-01

AUTHORS

V. E. Shiryaeva, A. A. Korolev, T. P. Popova, A. A. Kurganov

ABSTRACT

Retention factors were measured on silica gel, ethylene glycol dimethacrylate, and divinylbenzene monolithic columns for five groups of sorbates with different polarities. The retention factors of sorbates did not correlate directly with the polarity of the stationary phase probably because of differences in inner surface areas of sorbates accessible to sorbates. For the ethylene glycol dimethacrylate and divinylbenzene monoliths, the “methylene” selectivity was approximately the same and appreciably higher than for the silica gel monolith when helium was used as a carrier gas and approximately the same for monoliths of all types when the carrier gas was CO2. More... »

PAGES

1212-1216

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024409070292

DOI

http://dx.doi.org/10.1134/s0036024409070292

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044118699


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