The role played by an iodine-containing promoter in the formation of active polycrystalline silver catalyst surface View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-01

AUTHORS

V. S. Mal’kov, A. S. Knyazev, O. V. Vodyankina, I. K. Pak, E. V. Chernikov, A. N. Salanov, L. N. Kurina

ABSTRACT

The programmed temperature desorption method was used to study the interaction of oxygen with the surface of a polycrystalline silver catalyst promoted with iodine. Ethyl iodide almost did not interact with the unoxidized surface of silver. The adsorption of C2H5I on the oxidized catalyst surface resulted in the formation of two adsorbed iodine forms, silver iodide and iodine deeply dissolved in subsurface silver crystal lattice layers. The character of oxygen adsorption from the iodine-containing surface of the catalyst was determined by the amount and form of adsorbed iodine. In the presence of a iodine-containing promoter, the concentration of oxide-like oxygen sharply decreased, and the amount of strongly bound atomically adsorbed oxygen responsible for the selective transformation of ethylene glycol into glyoxal increased. More... »

PAGES

1088-1093

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024409070073

DOI

http://dx.doi.org/10.1134/s0036024409070073

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018568941


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