The influence of carrier gas pressure on the retention of sorbates on monolithic capillary columns in gas chromatography View Full Text


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Article Info

DATE

2009-01

AUTHORS

A. A. Korolev, V. E. Shiryaeva, T. P. Popova, A. V. Kozin, A. A. Kurganov

ABSTRACT

The influence of carrier gas pressure on the retention factor k′ of light hydrocarbons C1–C4 in a monolithic capillary column based on divinylbenzene was studied. It was shown that, for monolithic columns and nonideal carrier gases, the pressure dependence of lnk′ was nonlinear over a wide pressure range and could be described by the classic Everett equation. It was concluded that the competitive adsorption model failed to describe the experimental data correctly, especially for strongly retained sorbates and/or heavy carrier gases. More... »

PAGES

670-676

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024409040268

DOI

http://dx.doi.org/10.1134/s0036024409040268

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1015637620


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