The influence of the structure of some aromatic heterocyclic derivatives on their retention in reversed-phase high-performance liquid chromatography View Full Text


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Article Info

DATE

2009-01

AUTHORS

S. V. Kurbatova, B. R. Saifutdinov, O. G. Larionov, V. V. Meshkovaya

ABSTRACT

The chromatographic behavior of aromatic heterocyclic derivatives in reversed-phase high-performance liquid chromatography was investigated. The retention characteristics of the substances under the conditions of chromatography with water-acetonitrile mobile phases (retention factors, relative retentions, distribution coefficients, Henry adsorption constants, differences in the differential molar energy of sorption, and Gibbs energies of sorption) were determined. It was shown that the chromatographic retention of the sorbates depended on their molecular structure. The influence of the nature of heteroatoms and their number on the sorption of heterocyclic compounds was discussed. More... »

PAGES

471-477

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s003602440903025x

DOI

http://dx.doi.org/10.1134/s003602440903025x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027395611


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