Fe-Containing Intermetallic Compounds As Catalysts of Methane Conversion with Carbon Dioxide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-02

AUTHORS

L. V. Galaktionova, L. A. Arkatova, L. N. Kurina, E. I. Gorbunova, V. N. Belousova, Yu. S. Naiborodenko, N. G. Kasatskii, N. N. Golobokov

ABSTRACT

Systems based on iron and aluminum were studied in methane conversion with carbon dioxide. The systems were prepared by the method of self-propagating high-temperature synthesis. Massive iron did not exhibit noticeable catalytic activity in methane conversion with carbon dioxide. The deactivation of iron-containing intermetallic compounds was shown to occur because of the formation of the FeC and FeO phases, which screened the active centers of the catalyst surface. The suggestion was made that the active center of the dissociative adsorption of methane was the γ-Fe phase, which existed at the working temperature of methane conversion with carbon dioxide. More... »

PAGES

206-210

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024408020118

DOI

http://dx.doi.org/10.1134/s0036024408020118

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1106794463


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