The relative contributions of self-heating and chain branching to the kinetics of hydrogen oxidation outside the ignition region close to ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-01

AUTHORS

V. V. Azatyan, I. A. Bolod’yan, V. Yu. Navtsenya, Yu. N. Shebeko

ABSTRACT

It is shown that, in hydrogen-oxygen mixtures, under the conditions when the rate of reaction chain termination is higher than the rate of chain branching, the characteristic reaction time is hundreds of seconds even in the immediate vicinity of the third ignition limit. The self-heating of the mixtures therefore does not exceed several degrees and, contrary to the accepted views, cannot result in thermal combustion. Ignition observed in the third limit region is caused by a higher rate of chain branching compared with chain termination; that is, it is a chain reaction. Self-heating only becomes substantial during the development of chain combustion. More... »

PAGES

56-61

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s003602440801007x

DOI

http://dx.doi.org/10.1134/s003602440801007x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1049478041


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0915", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Interdisciplinary Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Structural Macrokinetics and Materials Science Problems, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Azatyan", 
        "givenName": "V. V.", 
        "id": "sg:person.012216615105.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012216615105.25"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "FGU VNIIPO MChS, Balashikha, Moscow oblast, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bolod\u2019yan", 
        "givenName": "I. A.", 
        "id": "sg:person.014317571565.68", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014317571565.68"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "FGU VNIIPO MChS, Balashikha, Moscow oblast, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Navtsenya", 
        "givenName": "V. Yu.", 
        "id": "sg:person.014141601153.21", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014141601153.21"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "FGU VNIIPO MChS, Balashikha, Moscow oblast, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shebeko", 
        "givenName": "Yu. N.", 
        "id": "sg:person.010322371441.18", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010322371441.18"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/s0010-2180(98)00150-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007845914"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0010-2180(71)80134-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016840765"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0010-2180(88)90086-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043856620"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0010-2180(88)90086-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043856620"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0010-2180(98)00167-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050525384"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.18321/ectj608", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1090713009"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2008-01", 
    "datePublishedReg": "2008-01-01", 
    "description": "It is shown that, in hydrogen-oxygen mixtures, under the conditions when the rate of reaction chain termination is higher than the rate of chain branching, the characteristic reaction time is hundreds of seconds even in the immediate vicinity of the third ignition limit. The self-heating of the mixtures therefore does not exceed several degrees and, contrary to the accepted views, cannot result in thermal combustion. Ignition observed in the third limit region is caused by a higher rate of chain branching compared with chain termination; that is, it is a chain reaction. Self-heating only becomes substantial during the development of chain combustion.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s003602440801007x", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1327871", 
        "issn": [
          "0036-0244", 
          "0044-4537"
        ], 
        "name": "Russian Journal of Physical Chemistry A", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "82"
      }
    ], 
    "name": "The relative contributions of self-heating and chain branching to the kinetics of hydrogen oxidation outside the ignition region close to the third limit", 
    "pagination": "56-61", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "ebb3bd255e4f39911bae1c59d76012f4ad2215c2815d377d6d96213fc6c89794"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s003602440801007x"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1049478041"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s003602440801007x", 
      "https://app.dimensions.ai/details/publication/pub.1049478041"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T00:15", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8695_00000508.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S003602440801007X"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s003602440801007x'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s003602440801007x'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s003602440801007x'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s003602440801007x'


 

This table displays all metadata directly associated to this object as RDF triples.

103 TRIPLES      21 PREDICATES      32 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s003602440801007x schema:about anzsrc-for:09
2 anzsrc-for:0915
3 schema:author Na5419ece2d69403faf467e3cad7afe3f
4 schema:citation https://doi.org/10.1016/0010-2180(88)90086-7
5 https://doi.org/10.1016/s0010-2180(71)80134-7
6 https://doi.org/10.1016/s0010-2180(98)00150-3
7 https://doi.org/10.1016/s0010-2180(98)00167-9
8 https://doi.org/10.18321/ectj608
9 schema:datePublished 2008-01
10 schema:datePublishedReg 2008-01-01
11 schema:description It is shown that, in hydrogen-oxygen mixtures, under the conditions when the rate of reaction chain termination is higher than the rate of chain branching, the characteristic reaction time is hundreds of seconds even in the immediate vicinity of the third ignition limit. The self-heating of the mixtures therefore does not exceed several degrees and, contrary to the accepted views, cannot result in thermal combustion. Ignition observed in the third limit region is caused by a higher rate of chain branching compared with chain termination; that is, it is a chain reaction. Self-heating only becomes substantial during the development of chain combustion.
12 schema:genre research_article
13 schema:inLanguage en
14 schema:isAccessibleForFree false
15 schema:isPartOf Ne13a08e781d24abe9da9290dd1b9dad6
16 Ne1913ba451e84474a88fc5e0ac6ba0b8
17 sg:journal.1327871
18 schema:name The relative contributions of self-heating and chain branching to the kinetics of hydrogen oxidation outside the ignition region close to the third limit
19 schema:pagination 56-61
20 schema:productId N4732316f165d4fb0986441b4dd80ad41
21 Na68daf3ccbde4ea18601e9700ea9338d
22 Na8df8601518d4c119826ed6346466593
23 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049478041
24 https://doi.org/10.1134/s003602440801007x
25 schema:sdDatePublished 2019-04-11T00:15
26 schema:sdLicense https://scigraph.springernature.com/explorer/license/
27 schema:sdPublisher N11f1e3777087496aa7c646a0b6774e13
28 schema:url http://link.springer.com/10.1134/S003602440801007X
29 sgo:license sg:explorer/license/
30 sgo:sdDataset articles
31 rdf:type schema:ScholarlyArticle
32 N0be0643851f347d3b7b5818bd3362c8f rdf:first sg:person.010322371441.18
33 rdf:rest rdf:nil
34 N11a959b55588439cb7223bb24757d93d rdf:first sg:person.014141601153.21
35 rdf:rest N0be0643851f347d3b7b5818bd3362c8f
36 N11f1e3777087496aa7c646a0b6774e13 schema:name Springer Nature - SN SciGraph project
37 rdf:type schema:Organization
38 N44e490238d474c568d720515745e24ee rdf:first sg:person.014317571565.68
39 rdf:rest N11a959b55588439cb7223bb24757d93d
40 N4732316f165d4fb0986441b4dd80ad41 schema:name readcube_id
41 schema:value ebb3bd255e4f39911bae1c59d76012f4ad2215c2815d377d6d96213fc6c89794
42 rdf:type schema:PropertyValue
43 Na5419ece2d69403faf467e3cad7afe3f rdf:first sg:person.012216615105.25
44 rdf:rest N44e490238d474c568d720515745e24ee
45 Na68daf3ccbde4ea18601e9700ea9338d schema:name dimensions_id
46 schema:value pub.1049478041
47 rdf:type schema:PropertyValue
48 Na8df8601518d4c119826ed6346466593 schema:name doi
49 schema:value 10.1134/s003602440801007x
50 rdf:type schema:PropertyValue
51 Nbf37a23df61b40c98708371adba20d2e schema:name FGU VNIIPO MChS, Balashikha, Moscow oblast, Russia
52 rdf:type schema:Organization
53 Ncfea67484f4745bdaff4a0fdd45784e2 schema:name FGU VNIIPO MChS, Balashikha, Moscow oblast, Russia
54 rdf:type schema:Organization
55 Ne13a08e781d24abe9da9290dd1b9dad6 schema:issueNumber 1
56 rdf:type schema:PublicationIssue
57 Ne1913ba451e84474a88fc5e0ac6ba0b8 schema:volumeNumber 82
58 rdf:type schema:PublicationVolume
59 Nf8f33a473ada4ad3bc23d6fa7a960f62 schema:name FGU VNIIPO MChS, Balashikha, Moscow oblast, Russia
60 rdf:type schema:Organization
61 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
62 schema:name Engineering
63 rdf:type schema:DefinedTerm
64 anzsrc-for:0915 schema:inDefinedTermSet anzsrc-for:
65 schema:name Interdisciplinary Engineering
66 rdf:type schema:DefinedTerm
67 sg:journal.1327871 schema:issn 0036-0244
68 0044-4537
69 schema:name Russian Journal of Physical Chemistry A
70 rdf:type schema:Periodical
71 sg:person.010322371441.18 schema:affiliation Nf8f33a473ada4ad3bc23d6fa7a960f62
72 schema:familyName Shebeko
73 schema:givenName Yu. N.
74 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010322371441.18
75 rdf:type schema:Person
76 sg:person.012216615105.25 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
77 schema:familyName Azatyan
78 schema:givenName V. V.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012216615105.25
80 rdf:type schema:Person
81 sg:person.014141601153.21 schema:affiliation Ncfea67484f4745bdaff4a0fdd45784e2
82 schema:familyName Navtsenya
83 schema:givenName V. Yu.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014141601153.21
85 rdf:type schema:Person
86 sg:person.014317571565.68 schema:affiliation Nbf37a23df61b40c98708371adba20d2e
87 schema:familyName Bolod’yan
88 schema:givenName I. A.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014317571565.68
90 rdf:type schema:Person
91 https://doi.org/10.1016/0010-2180(88)90086-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043856620
92 rdf:type schema:CreativeWork
93 https://doi.org/10.1016/s0010-2180(71)80134-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016840765
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1016/s0010-2180(98)00150-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007845914
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1016/s0010-2180(98)00167-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050525384
98 rdf:type schema:CreativeWork
99 https://doi.org/10.18321/ectj608 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090713009
100 rdf:type schema:CreativeWork
101 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
102 schema:name Institute of Structural Macrokinetics and Materials Science Problems, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia
103 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...