Transformations of C2-C4 alcohols on the surface of a copper catalyst View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-10

AUTHORS

A. A. Magaeva, G. V. Lyamina, N. N. Sudakova, L. P. Shilyaeva, O. V. Vodyankina

ABSTRACT

The interaction of monoatomic alcohols C2-C4 with the surface of a copper catalyst preliminarily oxidized under various conditions was studied by the temperature-programmed reaction method to determine the detailed mechanism of partial oxidation. The conditions of oxygen preadsorption on the surface of copper for the preparation of the desired products were determined. The selective formation of carbonyl compounds was shown to occur at the boundary between reduced and oxidized copper surface regions. The role played by Cu2O was the deep oxidation of alcohols to CO2. Alcohols with branched hydrocarbon structures experienced parallel partial oxidation and dehydrogenation, which was related to the high stability of intermediate keto-type compounds. More... »

PAGES

1613-1617

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024407100123

DOI

http://dx.doi.org/10.1134/s0036024407100123

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047230877


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Department of Structural Macrokinetics, Tomsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Tomsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Magaeva", 
        "givenName": "A. A.", 
        "id": "sg:person.0771164551.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0771164551.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Tomsk State University", 
          "id": "https://www.grid.ac/institutes/grid.77602.34", 
          "name": [
            "Tomsk State University, 634050, Tomsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lyamina", 
        "givenName": "G. V.", 
        "id": "sg:person.015652577273.77", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015652577273.77"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Tomsk State University", 
          "id": "https://www.grid.ac/institutes/grid.77602.34", 
          "name": [
            "Tomsk State University, 634050, Tomsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sudakova", 
        "givenName": "N. N.", 
        "id": "sg:person.015210570633.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015210570633.02"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Tomsk State University", 
          "id": "https://www.grid.ac/institutes/grid.77602.34", 
          "name": [
            "Tomsk State University, 634050, Tomsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shilyaeva", 
        "givenName": "L. P.", 
        "id": "sg:person.016066014225.07", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016066014225.07"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Tomsk State University", 
          "id": "https://www.grid.ac/institutes/grid.77602.34", 
          "name": [
            "Tomsk State University, 634050, Tomsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vodyankina", 
        "givenName": "O. V.", 
        "id": "sg:person.013671423573.17", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013671423573.17"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/0039-6028(82)90364-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013818717"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0039-6028(82)90364-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013818717"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b000253o", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030711173"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1019076415303", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038117589", 
          "https://doi.org/10.1023/a:1019076415303"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0039-6028(00)00881-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051478342"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2007-10", 
    "datePublishedReg": "2007-10-01", 
    "description": "The interaction of monoatomic alcohols C2-C4 with the surface of a copper catalyst preliminarily oxidized under various conditions was studied by the temperature-programmed reaction method to determine the detailed mechanism of partial oxidation. The conditions of oxygen preadsorption on the surface of copper for the preparation of the desired products were determined. The selective formation of carbonyl compounds was shown to occur at the boundary between reduced and oxidized copper surface regions. The role played by Cu2O was the deep oxidation of alcohols to CO2. Alcohols with branched hydrocarbon structures experienced parallel partial oxidation and dehydrogenation, which was related to the high stability of intermediate keto-type compounds.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0036024407100123", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1327871", 
        "issn": [
          "0036-0244", 
          "0044-4537"
        ], 
        "name": "Russian Journal of Physical Chemistry A", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "10", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "81"
      }
    ], 
    "name": "Transformations of C2-C4 alcohols on the surface of a copper catalyst", 
    "pagination": "1613-1617", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "e0fe1faf6f14e8f4593138ed3041c6786b1e4229a5537ae6ea5fa668c75568ab"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0036024407100123"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1047230877"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0036024407100123", 
      "https://app.dimensions.ai/details/publication/pub.1047230877"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T18:19", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8675_00000507.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S0036024407100123"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036024407100123'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036024407100123'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036024407100123'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036024407100123'


 

This table displays all metadata directly associated to this object as RDF triples.

105 TRIPLES      21 PREDICATES      31 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0036024407100123 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N4aa0134924034adfaf0bf16cedad09a7
4 schema:citation sg:pub.10.1023/a:1019076415303
5 https://doi.org/10.1016/0039-6028(82)90364-8
6 https://doi.org/10.1016/s0039-6028(00)00881-5
7 https://doi.org/10.1039/b000253o
8 schema:datePublished 2007-10
9 schema:datePublishedReg 2007-10-01
10 schema:description The interaction of monoatomic alcohols C2-C4 with the surface of a copper catalyst preliminarily oxidized under various conditions was studied by the temperature-programmed reaction method to determine the detailed mechanism of partial oxidation. The conditions of oxygen preadsorption on the surface of copper for the preparation of the desired products were determined. The selective formation of carbonyl compounds was shown to occur at the boundary between reduced and oxidized copper surface regions. The role played by Cu2O was the deep oxidation of alcohols to CO2. Alcohols with branched hydrocarbon structures experienced parallel partial oxidation and dehydrogenation, which was related to the high stability of intermediate keto-type compounds.
11 schema:genre research_article
12 schema:inLanguage en
13 schema:isAccessibleForFree false
14 schema:isPartOf N9d3fd7d4d64e497583b68e902ef863f4
15 Nfdf60d7f1e704e02bb58d6fa8ef26f53
16 sg:journal.1327871
17 schema:name Transformations of C2-C4 alcohols on the surface of a copper catalyst
18 schema:pagination 1613-1617
19 schema:productId N55c550045e1343e285ca04cf57c4d38b
20 N88a704ec3ab5447d9f7b2a623d8e56b7
21 Nb322662036a540118bf26c0d60e0a9bb
22 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047230877
23 https://doi.org/10.1134/s0036024407100123
24 schema:sdDatePublished 2019-04-10T18:19
25 schema:sdLicense https://scigraph.springernature.com/explorer/license/
26 schema:sdPublisher N1fda1027e398400e88c0bd8e62a7548e
27 schema:url http://link.springer.com/10.1134/S0036024407100123
28 sgo:license sg:explorer/license/
29 sgo:sdDataset articles
30 rdf:type schema:ScholarlyArticle
31 N07852042760e4e2d801c18d471fc5fe8 rdf:first sg:person.015652577273.77
32 rdf:rest N9765d919a2084cfaba9604ba520c76a8
33 N0f7106bfb7c84099867b5493e99c4b5c rdf:first sg:person.016066014225.07
34 rdf:rest Nf106e04dfdd14c9d9289138100fed101
35 N1fda1027e398400e88c0bd8e62a7548e schema:name Springer Nature - SN SciGraph project
36 rdf:type schema:Organization
37 N4aa0134924034adfaf0bf16cedad09a7 rdf:first sg:person.0771164551.28
38 rdf:rest N07852042760e4e2d801c18d471fc5fe8
39 N55c550045e1343e285ca04cf57c4d38b schema:name doi
40 schema:value 10.1134/s0036024407100123
41 rdf:type schema:PropertyValue
42 N88a704ec3ab5447d9f7b2a623d8e56b7 schema:name dimensions_id
43 schema:value pub.1047230877
44 rdf:type schema:PropertyValue
45 N9765d919a2084cfaba9604ba520c76a8 rdf:first sg:person.015210570633.02
46 rdf:rest N0f7106bfb7c84099867b5493e99c4b5c
47 N9d3fd7d4d64e497583b68e902ef863f4 schema:volumeNumber 81
48 rdf:type schema:PublicationVolume
49 Nb322662036a540118bf26c0d60e0a9bb schema:name readcube_id
50 schema:value e0fe1faf6f14e8f4593138ed3041c6786b1e4229a5537ae6ea5fa668c75568ab
51 rdf:type schema:PropertyValue
52 Nf106e04dfdd14c9d9289138100fed101 rdf:first sg:person.013671423573.17
53 rdf:rest rdf:nil
54 Nfdf60d7f1e704e02bb58d6fa8ef26f53 schema:issueNumber 10
55 rdf:type schema:PublicationIssue
56 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
57 schema:name Chemical Sciences
58 rdf:type schema:DefinedTerm
59 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
60 schema:name Physical Chemistry (incl. Structural)
61 rdf:type schema:DefinedTerm
62 sg:journal.1327871 schema:issn 0036-0244
63 0044-4537
64 schema:name Russian Journal of Physical Chemistry A
65 rdf:type schema:Periodical
66 sg:person.013671423573.17 schema:affiliation https://www.grid.ac/institutes/grid.77602.34
67 schema:familyName Vodyankina
68 schema:givenName O. V.
69 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013671423573.17
70 rdf:type schema:Person
71 sg:person.015210570633.02 schema:affiliation https://www.grid.ac/institutes/grid.77602.34
72 schema:familyName Sudakova
73 schema:givenName N. N.
74 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015210570633.02
75 rdf:type schema:Person
76 sg:person.015652577273.77 schema:affiliation https://www.grid.ac/institutes/grid.77602.34
77 schema:familyName Lyamina
78 schema:givenName G. V.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015652577273.77
80 rdf:type schema:Person
81 sg:person.016066014225.07 schema:affiliation https://www.grid.ac/institutes/grid.77602.34
82 schema:familyName Shilyaeva
83 schema:givenName L. P.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016066014225.07
85 rdf:type schema:Person
86 sg:person.0771164551.28 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
87 schema:familyName Magaeva
88 schema:givenName A. A.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0771164551.28
90 rdf:type schema:Person
91 sg:pub.10.1023/a:1019076415303 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038117589
92 https://doi.org/10.1023/a:1019076415303
93 rdf:type schema:CreativeWork
94 https://doi.org/10.1016/0039-6028(82)90364-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013818717
95 rdf:type schema:CreativeWork
96 https://doi.org/10.1016/s0039-6028(00)00881-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051478342
97 rdf:type schema:CreativeWork
98 https://doi.org/10.1039/b000253o schema:sameAs https://app.dimensions.ai/details/publication/pub.1030711173
99 rdf:type schema:CreativeWork
100 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
101 schema:name Department of Structural Macrokinetics, Tomsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Tomsk, Russia
102 rdf:type schema:Organization
103 https://www.grid.ac/institutes/grid.77602.34 schema:alternateName Tomsk State University
104 schema:name Tomsk State University, 634050, Tomsk, Russia
105 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...