The structural characteristics and homogeneity regions of solid phases in the digraphite fluoride-acetonitrile system View Full Text


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Article Info

DATE

2006-08

AUTHORS

D. V. Pinakov, K. A. Khaldoyanidi, G. N. Chekhova, V. A. Logvinenko, Yu. V. Shubin, V. P. Fadeeva

ABSTRACT

Studies by differential thermal analysis, X-ray structure analysis, and the Schreinemakers, visual-polymetric, gravimetric, and isopiestic methods showed that the digraphite fluoride (host)-acetonitrile (guest) system contained three clathrate phases with translation periods Ic = 9.47, 15.52, and 27.7 Å, which incongruently decomposed at 373.6, 430.1, and 530 K, and solid solutions based on the fluorinated matrix (Ic ≈ 6.05 Å). Low-temperature phase transitions were observed for the guest component and inclusion compounds. The activation energy of decomposition of the first-stage intercalate to a second-stage compound and gaseous acetonitrile was found to be 51.0 kJ/mol. More... »

PAGES

1198-1204

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036024406080036

DOI

http://dx.doi.org/10.1134/s0036024406080036

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031578278


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