Extraction of f Elements by Binary Extractants Based on 1,5-Bis[о-(dioxyphosphoryl)phenoxy]-3-Oxapentane Derivatives and Trioctylamine View Full Text


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Article Info

DATE

2018-12-10

AUTHORS

A. M. Safiulina, D. V. Ivanets, E. M. Kudryavtsev, D. V. Baulin, V. E. Baulin, A. Yu. Tsivadze

ABSTRACT

This is the first study of uranium(VI), thorium(IV), and lanthanum(III) extraction from nitric acid solutions in 1,2-dichloroethane (DCE) by binary extractants prepared from stoichiometric mixtures of diphosphonic acids, namely, 1,5-bis[o-(dioxyphosphoryl)phenoxy]-3-oxapentane or 1,5-bis[о-(dioxyphosphoryl)- n-ethylphenoxy]-3-oxapentane, and trioctylamine. The binary extractant comprised of 1,5-bis[о-(dioxyphosphoryl)-n-ethylphenoxy]-3-oxapentane and trioctylamine is found to selectively recover Th(IV) from solutions that contain both U(VI) and La(III), with separation factors exceeding 100. A method is developed for an efficient stripping of thorium(IV), uranium(VI), and lanthanum(III) from the saturated organic phase. Conditions are found for recovering the studied binary extractants after stripping to make them reusable. More... »

PAGES

1679-1683

References to SciGraph publications

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  • 2015-01. Phosphoryl-containing acidic podands as extractants for recovery of f-elements in RUSSIAN CHEMICAL BULLETIN
  • 2016-03-02. Separation and recovery of critical metal ions using ionic liquids in ADVANCES IN MANUFACTURING
  • 2015-01. Acidic phosphoryl podands as components of impregnation-type sorbents for 99Mo recovery from nitric acid solutions in RADIOCHEMISTRY
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