A Study of Сu(II) Complexes with Pyruvic Acid Nicotinoyl and Isonicotinoyl Hydrazones by EPR and X-ray Absorption Spectroscopy View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-11-16

AUTHORS

A. V. Pulya, I. I. Seifullina, L. S. Skorokhod, N. N. Efimov, E. A. Ugolkova, V. G. Vlasenko, A. L. Trigub, V. V. Minin

ABSTRACT

The composition and structure of the Cu2+ coordination cores in the previously synthesized [CuCl(HNPv)] · H2O, [CuCl(HIPv)] · H2O, [Cu(AOc)(HNPv)], [Cu(AOc)(HIPv)], [Cu(NO3)(HNPv)], and [Cu(NO3)(HIPv)] complexes, where HNPv and HIPv pyruvic acid nicotinoyl and isonicotinoyl hydrazones, respectively, have been determined. The binuclear complex [Cu2(HNPv)2(H2O)2(μ-Cl)] has been synthesized for the first time and characterized by elemental analysis and IR, EPR, and EXAFS spectroscopy. Its dimeric structure has been proved by magnetic susceptibility measurement and EPR. More... »

PAGES

1472-1477

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s003602361811013x

DOI

http://dx.doi.org/10.1134/s003602361811013x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1109916883


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