Synthesis, Crystal, and Molecular Structure of Bis(thiosemicarbazide)zinc(II) 1,5-Naphthalenedisulfonate Monohydrate [Zn(Tsc)2](1,5-Nds) · H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-07

AUTHORS

T. V. Koksharova, V. S. Sergienko, I. N. Polyakova, T. S. Skakun, M. D. Surazhskaya

ABSTRACT

Complex [Zn(Tsc)2](Nds) · H2O (I) (Tsc is thiosemicarbazide, NH2NHC(=S)NH2, and 1,5-Nds2–is the double-deprotonated anion of 1,5-naphthalenedisulfonic acid, C10H6(SO3)22-) has been synthesized and studied by IR spectroscopy, thermogravimetry, and X-ray diffraction analysis. The structural units of crystal I are complex cations [Zn(Tsc)2]2+, anions (Nds)2–, and crystallization water molecules. The Zn atom is coordinated along the vertices of the distorted tetrahedron by two sulfur atoms and two nitrogen atoms of two bidentate chelate (S,N) Tsc ligands. The structural units of crystal I are joined together by a branched network of the N–H···O hydrogen bonds involving independent donor hydrogen atoms of the NH2 and NH groups of Tsc molecules (nine of ten, except for the H(6A) atom), all six independent acceptor oxygen atoms of the SO3 groups of the Nds2– anions, and two acceptor hydrogen atoms and one donor oxygen atom of the water molecule. More... »

PAGES

887-893

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023618070100

DOI

http://dx.doi.org/10.1134/s0036023618070100

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1105979267


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Odessa I. I. Mechnikov National University", 
          "id": "https://www.grid.ac/institutes/grid.440557.7", 
          "name": [
            "Mechnikov Odessa National University, 65082, Odessa, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Koksharova", 
        "givenName": "T. V.", 
        "id": "sg:person.016311020231.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016311020231.06"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "All Russian Institute for Scientific and Technical Information", 
          "id": "https://www.grid.ac/institutes/grid.463015.5", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia", 
            "All-Russian Institute for Scientific and Technical Information, 125315, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sergienko", 
        "givenName": "V. S.", 
        "id": "sg:person.0656275315.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0656275315.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Polyakova", 
        "givenName": "I. N.", 
        "id": "sg:person.01021356734.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01021356734.64"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Odessa I. I. Mechnikov National University", 
          "id": "https://www.grid.ac/institutes/grid.440557.7", 
          "name": [
            "Mechnikov Odessa National University, 65082, Odessa, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Skakun", 
        "givenName": "T. S.", 
        "id": "sg:person.016145742300.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016145742300.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Surazhskaya", 
        "givenName": "M. D.", 
        "id": "sg:person.010322233010.62", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010322233010.62"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1039/b009851p", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006260969"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0365110x60001679", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008709052"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108768102003890", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012549006"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108270199012974", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013553002"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b902954k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023063503"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b902954k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023063503"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.molstruc.2010.07.031", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023555267"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108767307043930", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027786902"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c1ce05622k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034847422"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s1600536805003120", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037101552"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0277-5387(02)01399-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043864619"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b102729h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044449232"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s40242-014-3414-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046029032", 
          "https://doi.org/10.1007/s40242-014-3414-6"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp075456i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056073658"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp075456i", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056073658"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2018-07", 
    "datePublishedReg": "2018-07-01", 
    "description": "Complex [Zn(Tsc)2](Nds) \u00b7 H2O (I) (Tsc is thiosemicarbazide, NH2NHC(=S)NH2, and 1,5-Nds2\u2013is the double-deprotonated anion of 1,5-naphthalenedisulfonic acid, C10H6(SO3)22-) has been synthesized and studied by IR spectroscopy, thermogravimetry, and X-ray diffraction analysis. The structural units of crystal I are complex cations [Zn(Tsc)2]2+, anions (Nds)2\u2013, and crystallization water molecules. The Zn atom is coordinated along the vertices of the distorted tetrahedron by two sulfur atoms and two nitrogen atoms of two bidentate chelate (S,N) Tsc ligands. The structural units of crystal I are joined together by a branched network of the N\u2013H\u00b7\u00b7\u00b7O hydrogen bonds involving independent donor hydrogen atoms of the NH2 and NH groups of Tsc molecules (nine of ten, except for the H(6A) atom), all six independent acceptor oxygen atoms of the SO3 groups of the Nds2\u2013 anions, and two acceptor hydrogen atoms and one donor oxygen atom of the water molecule.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0036023618070100", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1004031", 
        "issn": [
          "0036-0236", 
          "0044-457X"
        ], 
        "name": "Russian Journal of Inorganic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "7", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "63"
      }
    ], 
    "name": "Synthesis, Crystal, and Molecular Structure of Bis(thiosemicarbazide)zinc(II) 1,5-Naphthalenedisulfonate Monohydrate [Zn(Tsc)2](1,5-Nds) \u00b7 H2O", 
    "pagination": "887-893", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "b780cdff2b316724f32681e4de1e9b89178790e1e46a97136bb48d12ed3d2273"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0036023618070100"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1105979267"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0036023618070100", 
      "https://app.dimensions.ai/details/publication/pub.1105979267"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T13:27", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8659_00000569.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1134%2FS0036023618070100"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036023618070100'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036023618070100'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036023618070100'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036023618070100'


 

This table displays all metadata directly associated to this object as RDF triples.

136 TRIPLES      21 PREDICATES      40 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0036023618070100 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N291fffd9d00c4c909ac29c4467e4a39c
4 schema:citation sg:pub.10.1007/s40242-014-3414-6
5 https://doi.org/10.1016/j.molstruc.2010.07.031
6 https://doi.org/10.1016/s0277-5387(02)01399-2
7 https://doi.org/10.1021/jp075456i
8 https://doi.org/10.1039/b009851p
9 https://doi.org/10.1039/b102729h
10 https://doi.org/10.1039/b902954k
11 https://doi.org/10.1039/c1ce05622k
12 https://doi.org/10.1107/s0108270199012974
13 https://doi.org/10.1107/s0108767307043930
14 https://doi.org/10.1107/s0108768102003890
15 https://doi.org/10.1107/s0365110x60001679
16 https://doi.org/10.1107/s1600536805003120
17 schema:datePublished 2018-07
18 schema:datePublishedReg 2018-07-01
19 schema:description Complex [Zn(Tsc)2](Nds) · H2O (I) (Tsc is thiosemicarbazide, NH2NHC(=S)NH2, and 1,5-Nds2–is the double-deprotonated anion of 1,5-naphthalenedisulfonic acid, C10H6(SO3)22-) has been synthesized and studied by IR spectroscopy, thermogravimetry, and X-ray diffraction analysis. The structural units of crystal I are complex cations [Zn(Tsc)2]2+, anions (Nds)2–, and crystallization water molecules. The Zn atom is coordinated along the vertices of the distorted tetrahedron by two sulfur atoms and two nitrogen atoms of two bidentate chelate (S,N) Tsc ligands. The structural units of crystal I are joined together by a branched network of the N–H···O hydrogen bonds involving independent donor hydrogen atoms of the NH2 and NH groups of Tsc molecules (nine of ten, except for the H(6A) atom), all six independent acceptor oxygen atoms of the SO3 groups of the Nds2– anions, and two acceptor hydrogen atoms and one donor oxygen atom of the water molecule.
20 schema:genre research_article
21 schema:inLanguage en
22 schema:isAccessibleForFree false
23 schema:isPartOf N08c0ef4ddefa4995abf379f103594e06
24 N4af08f5c4308401cbc4001746a7ec467
25 sg:journal.1004031
26 schema:name Synthesis, Crystal, and Molecular Structure of Bis(thiosemicarbazide)zinc(II) 1,5-Naphthalenedisulfonate Monohydrate [Zn(Tsc)2](1,5-Nds) · H2O
27 schema:pagination 887-893
28 schema:productId N02691b64d97c41979cad950e51fcb6b9
29 N7ceff089ab314efc89baf82143ab685f
30 Nb2914268d9084eb59ef6dfeb3a85d0b0
31 schema:sameAs https://app.dimensions.ai/details/publication/pub.1105979267
32 https://doi.org/10.1134/s0036023618070100
33 schema:sdDatePublished 2019-04-10T13:27
34 schema:sdLicense https://scigraph.springernature.com/explorer/license/
35 schema:sdPublisher N5703c6185e144fd4bf87723e19d2d471
36 schema:url https://link.springer.com/10.1134%2FS0036023618070100
37 sgo:license sg:explorer/license/
38 sgo:sdDataset articles
39 rdf:type schema:ScholarlyArticle
40 N02691b64d97c41979cad950e51fcb6b9 schema:name readcube_id
41 schema:value b780cdff2b316724f32681e4de1e9b89178790e1e46a97136bb48d12ed3d2273
42 rdf:type schema:PropertyValue
43 N08c0ef4ddefa4995abf379f103594e06 schema:issueNumber 7
44 rdf:type schema:PublicationIssue
45 N291fffd9d00c4c909ac29c4467e4a39c rdf:first sg:person.016311020231.06
46 rdf:rest Nc92748251a524f04965cc88923fc271b
47 N4af08f5c4308401cbc4001746a7ec467 schema:volumeNumber 63
48 rdf:type schema:PublicationVolume
49 N5703c6185e144fd4bf87723e19d2d471 schema:name Springer Nature - SN SciGraph project
50 rdf:type schema:Organization
51 N596954b6655d420dace05325143db184 rdf:first sg:person.01021356734.64
52 rdf:rest Nf241f627ae2e4196a4bd37e7a171f334
53 N7ceff089ab314efc89baf82143ab685f schema:name doi
54 schema:value 10.1134/s0036023618070100
55 rdf:type schema:PropertyValue
56 Nb2914268d9084eb59ef6dfeb3a85d0b0 schema:name dimensions_id
57 schema:value pub.1105979267
58 rdf:type schema:PropertyValue
59 Nc92748251a524f04965cc88923fc271b rdf:first sg:person.0656275315.49
60 rdf:rest N596954b6655d420dace05325143db184
61 Nf241f627ae2e4196a4bd37e7a171f334 rdf:first sg:person.016145742300.49
62 rdf:rest Nfd077ecfed544d0da169c2f492b955c2
63 Nfd077ecfed544d0da169c2f492b955c2 rdf:first sg:person.010322233010.62
64 rdf:rest rdf:nil
65 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
66 schema:name Chemical Sciences
67 rdf:type schema:DefinedTerm
68 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
69 schema:name Physical Chemistry (incl. Structural)
70 rdf:type schema:DefinedTerm
71 sg:journal.1004031 schema:issn 0036-0236
72 0044-457X
73 schema:name Russian Journal of Inorganic Chemistry
74 rdf:type schema:Periodical
75 sg:person.01021356734.64 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
76 schema:familyName Polyakova
77 schema:givenName I. N.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01021356734.64
79 rdf:type schema:Person
80 sg:person.010322233010.62 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
81 schema:familyName Surazhskaya
82 schema:givenName M. D.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010322233010.62
84 rdf:type schema:Person
85 sg:person.016145742300.49 schema:affiliation https://www.grid.ac/institutes/grid.440557.7
86 schema:familyName Skakun
87 schema:givenName T. S.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016145742300.49
89 rdf:type schema:Person
90 sg:person.016311020231.06 schema:affiliation https://www.grid.ac/institutes/grid.440557.7
91 schema:familyName Koksharova
92 schema:givenName T. V.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016311020231.06
94 rdf:type schema:Person
95 sg:person.0656275315.49 schema:affiliation https://www.grid.ac/institutes/grid.463015.5
96 schema:familyName Sergienko
97 schema:givenName V. S.
98 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0656275315.49
99 rdf:type schema:Person
100 sg:pub.10.1007/s40242-014-3414-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046029032
101 https://doi.org/10.1007/s40242-014-3414-6
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1016/j.molstruc.2010.07.031 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023555267
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1016/s0277-5387(02)01399-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043864619
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1021/jp075456i schema:sameAs https://app.dimensions.ai/details/publication/pub.1056073658
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1039/b009851p schema:sameAs https://app.dimensions.ai/details/publication/pub.1006260969
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1039/b102729h schema:sameAs https://app.dimensions.ai/details/publication/pub.1044449232
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1039/b902954k schema:sameAs https://app.dimensions.ai/details/publication/pub.1023063503
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1039/c1ce05622k schema:sameAs https://app.dimensions.ai/details/publication/pub.1034847422
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1107/s0108270199012974 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013553002
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1107/s0108767307043930 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027786902
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1107/s0108768102003890 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012549006
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1107/s0365110x60001679 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008709052
124 rdf:type schema:CreativeWork
125 https://doi.org/10.1107/s1600536805003120 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037101552
126 rdf:type schema:CreativeWork
127 https://www.grid.ac/institutes/grid.440557.7 schema:alternateName Odessa I. I. Mechnikov National University
128 schema:name Mechnikov Odessa National University, 65082, Odessa, Ukraine
129 rdf:type schema:Organization
130 https://www.grid.ac/institutes/grid.463015.5 schema:alternateName All Russian Institute for Scientific and Technical Information
131 schema:name All-Russian Institute for Scientific and Technical Information, 125315, Moscow, Russia
132 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
133 rdf:type schema:Organization
134 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
135 schema:name Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
136 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...