Electronic Structure and Electrooptical Properties of Radicals Formed upon Reduction of N-Alkyl 4,4′-Bipyridylium Salts View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-06

AUTHORS

V. V. Minin, M. I. Zakirov, N. N. Efimov, P. V. Mel’nikov, E. L. Nodova, B. I. Shapiro, V. M. Novotortsev

ABSTRACT

N-Alkyl 4,4'-bipyridylium salts were synthesized and characterized. Cyclic voltammetry investigation showed that monosubstited 4,4'-bipyridylium salts are prone to reversible single-electron reduction. The formal redox potentials vs. a saturated silver chloride electrode were determined for different potential sweep rates. High-resolution ESR spectra of the radical cations formed upon the reduction of N-substituted 4,4'- bipyridylium salts in acid media were measured and interpreted. The substituent structure and the type of anion in the molecule have a considerable effect on the spin density distribution, current–voltage characteristics, and elctrooptical properties. The applicability of monosubstituted 4,4'-bipyridylium salts as photoelectrochromic compounds was studied. More... »

PAGES

815-821

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023618060189

DOI

http://dx.doi.org/10.1134/s0036023618060189

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1105307250


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Minin", 
        "givenName": "V. V.", 
        "id": "sg:person.011207441575.56", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011207441575.56"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zakirov", 
        "givenName": "M. I.", 
        "id": "sg:person.010450062313.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010450062313.05"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Efimov", 
        "givenName": "N. N.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Moscow State University", 
          "id": "https://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Lomonosov Moscow State University of Fine Chemical Technology, 119571, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mel\u2019nikov", 
        "givenName": "P. V.", 
        "id": "sg:person.010327046671.12", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010327046671.12"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "International University of Nature, Society, and Man \u201cDubna,\u201d, 141980, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nodova", 
        "givenName": "E. L.", 
        "id": "sg:person.010234726503.79", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010234726503.79"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Moscow State University", 
          "id": "https://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Lomonosov Moscow State University of Fine Chemical Technology, 119571, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shapiro", 
        "givenName": "B. I.", 
        "id": "sg:person.07766266636.61", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07766266636.61"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Novotortsev", 
        "givenName": "V. M.", 
        "id": "sg:person.01013744635.03", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01013744635.03"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1246/bcsj.45.3309", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004664432"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0013-4686(77)85137-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020508454"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1149/1.2401732", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033388519"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jcc.540141112", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046672215"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0040-4020(81)85009-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050225530"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2018-06", 
    "datePublishedReg": "2018-06-01", 
    "description": "N-Alkyl 4,4'-bipyridylium salts were synthesized and characterized. Cyclic voltammetry investigation showed that monosubstited 4,4'-bipyridylium salts are prone to reversible single-electron reduction. The formal redox potentials vs. a saturated silver chloride electrode were determined for different potential sweep rates. High-resolution ESR spectra of the radical cations formed upon the reduction of N-substituted 4,4'- bipyridylium salts in acid media were measured and interpreted. The substituent structure and the type of anion in the molecule have a considerable effect on the spin density distribution, current\u2013voltage characteristics, and elctrooptical properties. The applicability of monosubstituted 4,4'-bipyridylium salts as photoelectrochromic compounds was studied.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0036023618060189", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1004031", 
        "issn": [
          "0036-0236", 
          "0044-457X"
        ], 
        "name": "Russian Journal of Inorganic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "63"
      }
    ], 
    "name": "Electronic Structure and Electrooptical Properties of Radicals Formed upon Reduction of N-Alkyl 4,4\u2032-Bipyridylium Salts", 
    "pagination": "815-821", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "8a9ce5f20e13c2bc3f858e4fc14c8147d91cc720a6bcf928b33d9bbaa0b259f1"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0036023618060189"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1105307250"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0036023618060189", 
      "https://app.dimensions.ai/details/publication/pub.1105307250"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T19:17", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8678_00000569.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1134%2FS0036023618060189"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036023618060189'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036023618060189'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036023618060189'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036023618060189'


 

This table displays all metadata directly associated to this object as RDF triples.

123 TRIPLES      21 PREDICATES      32 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0036023618060189 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nd6b2ac851fa2420aa0f1233e62a2084c
4 schema:citation https://doi.org/10.1002/jcc.540141112
5 https://doi.org/10.1016/0013-4686(77)85137-2
6 https://doi.org/10.1016/0040-4020(81)85009-0
7 https://doi.org/10.1149/1.2401732
8 https://doi.org/10.1246/bcsj.45.3309
9 schema:datePublished 2018-06
10 schema:datePublishedReg 2018-06-01
11 schema:description N-Alkyl 4,4'-bipyridylium salts were synthesized and characterized. Cyclic voltammetry investigation showed that monosubstited 4,4'-bipyridylium salts are prone to reversible single-electron reduction. The formal redox potentials vs. a saturated silver chloride electrode were determined for different potential sweep rates. High-resolution ESR spectra of the radical cations formed upon the reduction of N-substituted 4,4'- bipyridylium salts in acid media were measured and interpreted. The substituent structure and the type of anion in the molecule have a considerable effect on the spin density distribution, current–voltage characteristics, and elctrooptical properties. The applicability of monosubstituted 4,4'-bipyridylium salts as photoelectrochromic compounds was studied.
12 schema:genre research_article
13 schema:inLanguage en
14 schema:isAccessibleForFree false
15 schema:isPartOf Na1938fa1dbc244eeb73b7e9b8d6571e4
16 Nf815922b513f481ba1eb047319f8055e
17 sg:journal.1004031
18 schema:name Electronic Structure and Electrooptical Properties of Radicals Formed upon Reduction of N-Alkyl 4,4′-Bipyridylium Salts
19 schema:pagination 815-821
20 schema:productId N10deaad7d76240d38148a925c4bf52f9
21 N1b1236f6be28408c957d56e09282c279
22 Nad9b158a4cb649bd89e4cf8095c2d530
23 schema:sameAs https://app.dimensions.ai/details/publication/pub.1105307250
24 https://doi.org/10.1134/s0036023618060189
25 schema:sdDatePublished 2019-04-10T19:17
26 schema:sdLicense https://scigraph.springernature.com/explorer/license/
27 schema:sdPublisher N64afc08c8150428cb21508a61c8c9b71
28 schema:url https://link.springer.com/10.1134%2FS0036023618060189
29 sgo:license sg:explorer/license/
30 sgo:sdDataset articles
31 rdf:type schema:ScholarlyArticle
32 N0e046da815db455e9b2b6e1eece69401 rdf:first sg:person.07766266636.61
33 rdf:rest Nc885cf40d5424b0f841f2f5d3824b9e5
34 N10deaad7d76240d38148a925c4bf52f9 schema:name doi
35 schema:value 10.1134/s0036023618060189
36 rdf:type schema:PropertyValue
37 N1ae722dfeeb049c9a31dbe37e0471f93 rdf:first sg:person.010327046671.12
38 rdf:rest Na633b8b983b2466c88f1126b43a93c46
39 N1b1236f6be28408c957d56e09282c279 schema:name readcube_id
40 schema:value 8a9ce5f20e13c2bc3f858e4fc14c8147d91cc720a6bcf928b33d9bbaa0b259f1
41 rdf:type schema:PropertyValue
42 N56cae2e2449a44e5ad969f1d45241dc5 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
43 schema:familyName Efimov
44 schema:givenName N. N.
45 rdf:type schema:Person
46 N64afc08c8150428cb21508a61c8c9b71 schema:name Springer Nature - SN SciGraph project
47 rdf:type schema:Organization
48 N6b16c76547964edf978b57f9177be58a rdf:first sg:person.010450062313.05
49 rdf:rest Nb65f6664ac2e4039a3671e49e6f8ef45
50 N877f70f2c16e4d399bed5a22b432cb32 schema:name International University of Nature, Society, and Man “Dubna,”, 141980, Moscow, Russia
51 rdf:type schema:Organization
52 Na1938fa1dbc244eeb73b7e9b8d6571e4 schema:issueNumber 6
53 rdf:type schema:PublicationIssue
54 Na633b8b983b2466c88f1126b43a93c46 rdf:first sg:person.010234726503.79
55 rdf:rest N0e046da815db455e9b2b6e1eece69401
56 Nad9b158a4cb649bd89e4cf8095c2d530 schema:name dimensions_id
57 schema:value pub.1105307250
58 rdf:type schema:PropertyValue
59 Nb65f6664ac2e4039a3671e49e6f8ef45 rdf:first N56cae2e2449a44e5ad969f1d45241dc5
60 rdf:rest N1ae722dfeeb049c9a31dbe37e0471f93
61 Nc885cf40d5424b0f841f2f5d3824b9e5 rdf:first sg:person.01013744635.03
62 rdf:rest rdf:nil
63 Nd6b2ac851fa2420aa0f1233e62a2084c rdf:first sg:person.011207441575.56
64 rdf:rest N6b16c76547964edf978b57f9177be58a
65 Nf815922b513f481ba1eb047319f8055e schema:volumeNumber 63
66 rdf:type schema:PublicationVolume
67 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
68 schema:name Chemical Sciences
69 rdf:type schema:DefinedTerm
70 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
71 schema:name Physical Chemistry (incl. Structural)
72 rdf:type schema:DefinedTerm
73 sg:journal.1004031 schema:issn 0036-0236
74 0044-457X
75 schema:name Russian Journal of Inorganic Chemistry
76 rdf:type schema:Periodical
77 sg:person.01013744635.03 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
78 schema:familyName Novotortsev
79 schema:givenName V. M.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01013744635.03
81 rdf:type schema:Person
82 sg:person.010234726503.79 schema:affiliation N877f70f2c16e4d399bed5a22b432cb32
83 schema:familyName Nodova
84 schema:givenName E. L.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010234726503.79
86 rdf:type schema:Person
87 sg:person.010327046671.12 schema:affiliation https://www.grid.ac/institutes/grid.14476.30
88 schema:familyName Mel’nikov
89 schema:givenName P. V.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010327046671.12
91 rdf:type schema:Person
92 sg:person.010450062313.05 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
93 schema:familyName Zakirov
94 schema:givenName M. I.
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010450062313.05
96 rdf:type schema:Person
97 sg:person.011207441575.56 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
98 schema:familyName Minin
99 schema:givenName V. V.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011207441575.56
101 rdf:type schema:Person
102 sg:person.07766266636.61 schema:affiliation https://www.grid.ac/institutes/grid.14476.30
103 schema:familyName Shapiro
104 schema:givenName B. I.
105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07766266636.61
106 rdf:type schema:Person
107 https://doi.org/10.1002/jcc.540141112 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046672215
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1016/0013-4686(77)85137-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020508454
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1016/0040-4020(81)85009-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050225530
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1149/1.2401732 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033388519
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1246/bcsj.45.3309 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004664432
116 rdf:type schema:CreativeWork
117 https://www.grid.ac/institutes/grid.14476.30 schema:alternateName Moscow State University
118 schema:name Lomonosov Moscow State University of Fine Chemical Technology, 119571, Moscow, Russia
119 rdf:type schema:Organization
120 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
121 schema:name Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
122 Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia
123 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...