New double complex salt [PdEn2]3[Rh(NO2)6]2 · 2.67H2O: Synthesis, crystal structure, and thermal properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-07

AUTHORS

A. K. Kirilovich, P. E. Plyusnin, D. A. Piryazev, S. A. Gromilov, S. V. Korenev

ABSTRACT

The crystal structure of the double complex salt (DCS) [PdEn2]3[Rh(NO2)6]2 • 2.67H2O (I) has been determined by X-ray diffraction. Crystals are triclinic, space group P1¯\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$P\bar 1$$\end{document}, Z = 4, a = 9.2331(3) Å, b = 9.9136(4) Å, c = 13.7824(5) Å, α = 84.3230(14)°, β = 89.9655(14)°, γ = 66.7272(13)°, V = 1152.19(7) Å3, ρcalcd = 2.141 g/cm3, R = 0.0279. The thermal behavior of complex salt I has been studied in various gas atmospheres. The end product of thermolysis in reductive atmosphere is a mixture of Pd0.45Rh0.55 and Pd0.95Rh0.05 solid solutions. The end product of thermolysis in an inert atmosphere is a homogeneous Pd0.6Rh0.4 solid solution. More... »

PAGES

886-892

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023617070099

DOI

http://dx.doi.org/10.1134/s0036023617070099

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1091051567


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