Double complex salts [Au(En)2][Ir(NO2)6] • nH2O (n = 0, 2), [Au(En)2][Ir(NO2)6]x[Rh(NO2)6]1–x • nH2O (x = 0.25, 0.5, 0.75): Synthesis, structure, ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-01

AUTHORS

E. V. Makotchenko, P. E. Plyusnin, Yu. V. Shubin, I. A. Baidina, I. V. Korol’kov, L. A. Sheludyakova, S. V. Korenev

ABSTRACT

The double complex salts [Au(En)2][Ir(NO2)6] • 2H2O (I) and [Au(En)2][Ir(NO2)6] (II) and solid solutions [Au(En)2][Ir(NO2)6]x[Rh(NO2)6]1–x • nH2O, where x = 0.25, 0.5, 0.75, were prepared and characterized by powder X-ray diffraction, IR spectroscopy, elemental analysis, and DTA. The crystal structures were determined by X-ray diffraction. The thermal behavior of compounds under reducing atmosphere was studied. The final products of thermolysis were found to be two-phase mixtures consisting of nano-sized pure gold particles (~55 nm) and particles of Au–Ir–Rh solid solutions (~3 nm). More... »

PAGES

12-21

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023617010119

DOI

http://dx.doi.org/10.1134/s0036023617010119

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1083892542


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