Ontology type: schema:ScholarlyArticle
2016-09
AUTHORSV. V. Popov, A. P. Menushenkov, Ya. V. Zubavichus, A. A. Yaroslavtsev, D. S. Leshchev, E. S. Kulik, A. A. Yastrebtsev, A. A. Pisarev, S. A. Korovin, N. A. Tsarenko
ABSTRACTThe crystal and local structures of compounds formed in the Dy2O3–HfO2 system (at molar ratios from 1: 3 to 3: 1) in the course of isothermal annealing of X-ray amorphous mixed hydroxides at temperatures up to 1600°C have been studied. At the molar ratio Dy2O3: HfO2 from 1: 3 to 1: 1, crystallization leads to formation of single-phase defect fluorite solid solutions nDy2O3 ∙ mHfO2 with clearly pronounced nonequivalence of parameters of local environment of Dy3+ and Hf4+ cations. It has been found that Dy2H2O7 (Dy2O3: HfO2 = 1: 2) samples have a tendency to pyrochlore-type ordering in both the cationic and anionic sublattices. More... »
PAGES1135-1143
http://scigraph.springernature.com/pub.10.1134/s0036023616090175
DOIhttp://dx.doi.org/10.1134/s0036023616090175
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