New structural type in the chemistry of bismuth(III) polynuclear halide complexes: Synthesis and crystal structure of (H3O)3(diquat)6{[BiBr5]}6[BiBr6] • 2H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-08

AUTHORS

S. A. Adonin, I. D. Gorokh, D. G. Samsonenko, I. V. Korol’kov, M. N. Sokolov, V. P. Fedin

ABSTRACT

Complex (H3O)3(diquat)6{[BiBr5]}6[BiBr6] • 2H2O (I) has been prepared by the reaction between [BiBr6]3– and diaqua(1,1'-diethylene-2,2'-bipyridynium dibromide) in 2 M HBr and has been characterized by X-ray diffraction. The anionic part of compound I is formed by coordination polymeric anions {[BiBr5]–}n built of {BiBr6} octahedral blocks, which are joined by the μ2-bridge bromide ligands into infinite zigzag chains. The resulting complex belongs to new structural type among bismuth halide complexes. More... »

PAGES

958-963

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023616080027

DOI

http://dx.doi.org/10.1134/s0036023616080027

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https://app.dimensions.ai/details/publication/pub.1004879968


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