Interaction between hydrofluorosilicic acid and 1,10-phenanthroline: Hydrolytic stability of chelate complexes of silicon tetrafluoride with bidentate N-donors View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-07-22

AUTHORS

V. O. Gel’mbol’dt, V. Yu. Anisimov, M. S. Fonar’

ABSTRACT

Hexafluorosilicate (LH2)SiF6 and the cis-[SiF4(L)] chelate complex characterized by 19F NMR are products of reaction between hydrofluorosilicic acid and 1,10-phenanthroline (L). XRD findings show that the structure of (LH2)SiF6 is stabilized by NH···F hydrogen bonds (N···F 2.618(4), 2.676(4) Å) and CH···F contacts. The relative resistance of the cis-[SiF4(L)] complex to hydrolysis is associated with the chelate effect. More... »

PAGES

822-825

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023616070056

DOI

http://dx.doi.org/10.1134/s0036023616070056

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030978111


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