Malonatobenzhydrazidediaquacobalt(II) hydrate: Synthesis, crystal and molecular structures View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-04

AUTHORS

A. S. Antsyshkina, T. V. Koksharova, G. G. Sadikov, V. S. Sergienko, T. V. Mandzii

ABSTRACT

The coordination compound [Co(L)(Mal)(H2O)2]H2O (I) (L is benzhydrazide, H2Mal is malonic acid) has been synthesized and studied by IR spectroscopy, thermogravimetry, and X-ray diffraction. Crystals are triclinic, a = 7.610(4) Å, b = 7.854(2) Å, c = 12.751(2) Å, α = 75.12(3)°, β = 88.01(3)°, γ = 80.26(3)°, Z = 2, space group . The structure is molecular. The Co2+ atom has a distorted octahedral coordination. The Co-O and Co-N bond lengths are 2.031-2.129(4) and 2.157(5) Å, respectively. The endocyclic O1Co1N1 bond angles are 77.3(2)° and 90.0(2)° in the five- and six-membered chelate rings, respectively. Molecules of complex I are linked via a great number of hydrogen bonds. The C…C contacts between phenyl rings additionally strengthen the structure. More... »

PAGES

434-441

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023616040045

DOI

http://dx.doi.org/10.1134/s0036023616040045

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1020288813


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