Ontology type: schema:ScholarlyArticle
2016-02
AUTHORSV. V. Popov, A. P. Menushenkov, Ya. V. Zubavichus, A. S. Sharapov, V. A. Kabanova, A. A. Yastrebtsev, L. A. Arzhatkina, N. A. Tsarenko, A. M. Strel’nikova, V. V. Kurilkin
ABSTRACTCerium monoaluminate Ce1-x3+ Cex4+ AlO3+x/2 powders with low contents of Ce4+ cations (х ~ 0.052) were synthesized. A set of modern local structure sensitive methods of analysis, including X-ray absorption spectroscopy and Raman spectroscopy, were used to study the crystal, local, and electronic structures of the synthesized compounds. The degree of reduction and the thermal stability to oxidation of reduced powders depend not only on the reduction conditions but also on the conditions of heat pretreatment of the initial samples. It was concluded that the reaction 4CeAlO3 + O2 ↔ 4CeO2 + 2Al2O3 is reversible. More... »
PAGES225-231
http://scigraph.springernature.com/pub.10.1134/s0036023616020170
DOIhttp://dx.doi.org/10.1134/s0036023616020170
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