Molecular and crystal structure, and stability of 4-bromobenzyltriphenylphosphonium diiodobromide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-02

AUTHORS

M. S. Chernov’yants, I. V. Burykin, Z. A. Starikova, A. A. Rassoshenko

ABSTRACT

Complexation in system 4-bromobenzyltriphenylphosphonium bromide–molecular iodine in chloroform has been studied. The limit number of iodine molecules coordinated by 4-bromobenzyltriphenylphosphonium bromide in solution and the stability constant of the complex have been determined by a spectrophotometric method using iodine average number functions. According to the X-ray diffraction data, the crystal structure of the charge transfer complex is formed by anion BrI2− and cation [(C6H5)3PCH2C6H4Br]+. In a crystal, translationally identical cations C25H21BrP+ form stacks along the y axis. Diiodobromide anions dimerized due to the I–I shortened contacts are located between the stacks. More... »

PAGES

217-220

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023616020054

DOI

http://dx.doi.org/10.1134/s0036023616020054

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042655580


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