Synthesis, IR-spectroscopic study and crystal structure of tris(benzohydrazide)nickel(II) dichloride dihydrate [Ni(L)3]Cl2 · 2H2O View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-01

AUTHORS

A. S. Antsyshkina, T. V. Koksharova, V. S. Sergienko, T. V. Mandzii, G. G. Sadikov

ABSTRACT

Coordination compound [Ni(L)3]Cl2 · 2H2O (L is benzohydrazide) has been synthesized and studied by IR spectroscopy and X-ray diffraction analysis. According to X-ray diffraction, one of the Cl– ions is disordered over two nonequivalent positions. The crystals are monoclinic, a = 15.423(3) Å, b = 9.697(2) Å, c = 18.893(4) Å, ß = 105.99(3)°, space group P21/c, Z = 4. The structural units of the crystal are complex cations [Ni(L)3]2+, in which ligands L are coordinated to the central atom bidentately chelating the metal atoms through the O and N atoms of the hydrazide moiety (Ni–O 2.036(4), 2.051(5), 2.047(5); Ni–N 2.095(5), 2.089(6), 2.097(6) Å). The structural units of the crystal are joined together by cation–anion electrostatic interactions and hydrogen bonds, which involve both H2O molecules, both Cl– anions and the N atoms of chelate rings of the complex cation. More... »

PAGES

33-37

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023616010046

DOI

http://dx.doi.org/10.1134/s0036023616010046

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1008540559


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