Ontology type: schema:ScholarlyArticle
2015-12
AUTHORSA. V. Rotov, E. A. Ugolkova, N. N. Efimov, A. G. Beyrakhov, V. V. Minin
ABSTRACTCompounds CuL2, where L = R1N(O)–(O)CR2, R1 = C6H5, R2 = C6H5 (I); R1 = C6H5, R2 = CH3 (II); or R1 = 2,4,6-(CH3)3C6H2, R2 = CH3 (III) have been structurally studied by electron paramagnetic resonance (EPR) in methylene chloride. Spectra of two forms of the compounds, which according to the EPR data are mononuclear, are observed in all solutions at room temperature. In frozen solutions of complexes I and II, spectra of monomeric and dimeric forms of the complex are recorded; in a frozen solution of III, spectra of two monomeric forms of the complex. The absence of dimers in the frozen solution of III is explained by the presence of steric hindrances for the rapprochement of monomeric complexes. Relative concentrations of the forms and their magnetic resonance parameters have been determined using mathematical modeling of the shape of the EPR line. More... »
PAGES1556-1559
http://scigraph.springernature.com/pub.10.1134/s0036023615120207
DOIhttp://dx.doi.org/10.1134/s0036023615120207
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1009031121
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Inorganic Chemistry",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Science, Leninskii pr. 31, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Rotov",
"givenName": "A. V.",
"id": "sg:person.010424144647.30",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010424144647.30"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Science, Leninskii pr. 31, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Ugolkova",
"givenName": "E. A.",
"id": "sg:person.015265162315.78",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015265162315.78"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Science, Leninskii pr. 31, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Efimov",
"givenName": "N. N.",
"id": "sg:person.01024204401.44",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01024204401.44"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Science, Leninskii pr. 31, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Beyrakhov",
"givenName": "A. G.",
"type": "Person"
},
{
"affiliation": {
"alternateName": "Russian Academy of Sciences",
"id": "https://www.grid.ac/institutes/grid.4886.2",
"name": [
"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Science, Leninskii pr. 31, 119991, Moscow, Russia"
],
"type": "Organization"
},
"familyName": "Minin",
"givenName": "V. V.",
"id": "sg:person.011207441575.56",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011207441575.56"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1134/s0036023615070128",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1009182484",
"https://doi.org/10.1134/s0036023615070128"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf02496255",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1041280244",
"https://doi.org/10.1007/bf02496255"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf02496255",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1041280244",
"https://doi.org/10.1007/bf02496255"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1107/s0108270100001025",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1041354505"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s0036023613020216",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1048177962",
"https://doi.org/10.1134/s0036023613020216"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s0036023614120201",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1048449910",
"https://doi.org/10.1134/s0036023614120201"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0020-1693(00)93409-1",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1048968682"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1063/1.1726439",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1057792982"
],
"type": "CreativeWork"
}
],
"datePublished": "2015-12",
"datePublishedReg": "2015-12-01",
"description": "Compounds CuL2, where L = R1N(O)\u2013(O)CR2, R1 = C6H5, R2 = C6H5 (I); R1 = C6H5, R2 = CH3 (II); or R1 = 2,4,6-(CH3)3C6H2, R2 = CH3 (III) have been structurally studied by electron paramagnetic resonance (EPR) in methylene chloride. Spectra of two forms of the compounds, which according to the EPR data are mononuclear, are observed in all solutions at room temperature. In frozen solutions of complexes I and II, spectra of monomeric and dimeric forms of the complex are recorded; in a frozen solution of III, spectra of two monomeric forms of the complex. The absence of dimers in the frozen solution of III is explained by the presence of steric hindrances for the rapprochement of monomeric complexes. Relative concentrations of the forms and their magnetic resonance parameters have been determined using mathematical modeling of the shape of the EPR line.",
"genre": "research_article",
"id": "sg:pub.10.1134/s0036023615120207",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1004031",
"issn": [
"0036-0236",
"0044-457X"
],
"name": "Russian Journal of Inorganic Chemistry",
"type": "Periodical"
},
{
"issueNumber": "12",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "60"
}
],
"name": "Influence of ligand structure on the dimerization of copper(II) N-substituted hydroxamates according to EPR data",
"pagination": "1556-1559",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"2b0660223886bdf7913ac7511b6ba305a24232b87fa2d6003b435c20c8245e1d"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1134/s0036023615120207"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1009031121"
]
}
],
"sameAs": [
"https://doi.org/10.1134/s0036023615120207",
"https://app.dimensions.ai/details/publication/pub.1009031121"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-10T19:06",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8678_00000503.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1134/S0036023615120207"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036023615120207'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036023615120207'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036023615120207'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036023615120207'
This table displays all metadata directly associated to this object as RDF triples.
113 TRIPLES
21 PREDICATES
34 URIs
19 LITERALS
7 BLANK NODES