New aerogels chemically modified with amino complexes of bivalent copper View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-12

AUTHORS

S. A. Lermontov, N. A. Sipyagina, A. N. Malkova, A. E. Baranchikov, A. A. Sidorov, N. N. Efimov, E. A. Ugolkova, V. V. Minin, V. K. Ivanov, I. L. Eremenko

ABSTRACT

The reaction of copper(II) pivalate with aminopropyltrimethoxysilane in molar ratio Cu(II): RNH2 = 1: 4 leads to the corresponding complex 1. The combined gelation of complex 1 and Si(OCH3)4 produces lyogels whose structure incorporates Cu(II). The supercritical drying of the lyogels in CO2 results in aerogels with specific surface area up to 260 m2/g containing bivalent copper. Drying of lyogels under supercritical conditions in isopropanol and methanol leads to reduction of Cu(II) into metal state. More... »

PAGES

1459-1463

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023615120177

DOI

http://dx.doi.org/10.1134/s0036023615120177

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018783778


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