Electrochemical synthesis, structure, and photoluminescent properties of copper, zinc, and cadmium mixed-ligand complexes View Full Text


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Article Info

DATE

2015-12

AUTHORS

D. A. Garnovskii, A. S. Antsyshkina, N. I. Makarova, V. G. Vlasenko, G. G. Sadikov, V. S. Sergienko, Ya. V. Zubavichus, S. I. Levchenkov, A. I. Uraev, A. S. Burlov

ABSTRACT

Copper(II), zinc(II), and cadmium(II) mixed-ligand complexes [M(L)(L1)], (M = Cu (I), Cd (III)), [Zn(L)(L1)(H2O)] (II) and [Cd(L)(L2)] (IV)) on the basis of N-(2-{[1-phenyl-3-methyl-5-oxo-1,5-dihydro-4H-pyrazol-4-ylidene)methyl]amino}phenyl)-4-methylbenzenesulfonamide (H2L), 2-amino-1-ethylbenzimidazole (L1), and 2-aminopyrazine (L2) were prepared by electrochemical method. The composition and structure of the obtained compounds were proved by the data of C, H, N, S elemental analysis, IR and 1H NMR spectroscopy (for compounds II–IV), X-ray absorption spectroscopy (for compounds I and II), and magnetochemical measurements (for compound I), photoluminescent properties of complexes II–IV were also studied. The structure of compound II was determined by X-ray diffraction analysis. More... »

PAGES

1528-1536

References to SciGraph publications

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