Structural, EPR spectroscopic, and magnetochemical study of hydrogen-bonded dimeric copper(II) complexes with hetaryl hydrazones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-09-02

AUTHORS

S. I. Levchenkov, L. D. Popov, N. N. Efimov, V. V. Minin, E. A. Ugolkova, G. G. Aleksandrov, Z. A. Starikova, I. N. Shcherbakov, A. M. Ionov, V. A. Kogan

ABSTRACT

The copper(II) complexes [CuL1(NO3)] · CH3OH and [CuL2Cl] · CH3OH (L1 is 3,5-di-tert-butylsalicylal 1′-phthalazinyl hydrazone, and L2 is 2-N-tosylaminobenzal 2-imidazolinyl hydrazone) forming hydrogen-bonded dimers in a crystal were synthesized. A weak antiferromagnetic exchange interaction transmitted through extensive linkers incorporating the N–H···O hydrogen bond (2J is–3.0 and–2.6 cm–1, respectively) was recognized by EPR spectroscopy and low-temperature magnetochemistry. More... »

PAGES

1129-1136

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023615040129

DOI

http://dx.doi.org/10.1134/s0036023615040129

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034567888


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