Gadolinium(III) complexation with modified polymers according to ESR data View Full Text


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Article Info

DATE

2014-11-26

AUTHORS

A. V. Mikhailova, V. P. Dedkova, O. P. Shvoeva, Ya. I. Shcherbakova, N. N. Efimov, E. A. Ugolkova, A. A. Grechnikov, S. B. Savvin, V. V. Minin

ABSTRACT

Gadolinium(III) sorption and complexation with azo reagents (ORs) derived from chromotropic acid at pH 5 and ratio Gd(III) : OR = 1 : 1 was studied by ESR spectrometry. Solid phase used is polymeric fine-fibered materials filled with highly dispersed AV-17 anion-exchange resin. In the used systems, reagents containing o-sulfo-o′-hydroxyazo group show maximal complexing ability; Gd(III) sorption as a complex with OR formed in solution is considerably larger than metal sorption on a polymer with immobilized reagent. The features of ESR spectrum of Gd(III) ion with low-symmetry environment are discussed. More... »

PAGES

1485-1490

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023614120183

DOI

http://dx.doi.org/10.1134/s0036023614120183

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012951364


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