Synthesis, crystal and molecular structure of [Co(L)3](OH)Cl · H3Ssal) · H2O, where L is benzhydrazide and H3Ssal is 5-sulfosalycilic acid View Full Text


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Article Info

DATE

2014-12

AUTHORS

A. S. Antsyshkina, T. V. Koksharova, V. S. Sergienko, T. V. Mandzii, G. G. Sadikov

ABSTRACT

The coordination compound [Co(L)3](OH)Cl(H3Ssal) · H2O (I) (L is benzhydrazide, and H3Ssal is 5-sulfosalycilic acid) has been synthesized and studied by IR spectroscopy and X-ray diffraction. Orange crystals are triclinic: a = 9.948(2) Å, b = 12.288(3) Å, c = 14.710(3) Å, α = 109.39(3)°, β = 95.60(3)°, γ = 110.38(3)°, V = 1668.7(6) Å3, Z = 2, space group Structural units of compound I are complex CoL32+ cations, OH− and Cl− anions, sulfosalycilic acid molecules, and an H2O molecule disordered over two positions and linked to each other by hydrogen bonds. Phenyl rings participate in π-π-stacking interaction with the formation of centrosymmetric dimers. More... »

PAGES

1417-1423

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023614120031

DOI

http://dx.doi.org/10.1134/s0036023614120031

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032079421


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