Coordination compounds of dysprosium(III) with 3-methyl-1-phenyl-4-formylpyrazol-5-one diacyldihydrazones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-11

AUTHORS

O. V. Konnik, V. F. Shul’gin, Z. Z. Bekirova, Zh. V. Dobrokhotova, N. N. Efimov, G. G. Aleksandrov, I. L. Eremenko, V. M. Novotortsev

ABSTRACT

Coordination compounds of dysprosium(III) with diacyldihydrazones of saturated dicarboxylic acids, imino-, oxo-, and thiodiacetic acids, and 3-methyl-1-phenyl-4-formylpyrazol-5-one (H4L) are described. [Dy2(H2LO)3] · 7.5CH3OH · 3H2O was subjected to X-ray diffraction analysis: space group , a = 17.349(1) Å, c = 65.669(4) Å, Z = 6, R = 0.076, Rw = 0.243 (5301 reflections with I ≥ 2σ(I)). The complex is established to have a binuclear structure and contain dysprosium ions linked via three bridging ligands. The coordination polyhedron of the Dy atom had a three-capped trigonal prism geometry. The magnetic properties of the synthesized complexes were studied. More... »

PAGES

1237-1243

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023614110126

DOI

http://dx.doi.org/10.1134/s0036023614110126

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012281840


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