Osmium dimethyl sulfoxide complexes: Synthesis and properties of [H(dmso)2][OsIII(dmso)2Br4] View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-07

AUTHORS

O. V. Rudnitskaya, E. K. Kultyshkina, E. V. Dobrokhotova, N. N. Efimov, E. A. Ugolkova, M. V. Ovcharov, V. V. Minin

ABSTRACT

The reaction of H2[OsBr6] with DMSO in ethanol solution resulted in DMSO complex [H(dmso-O)2][OsIII(dmso-S)2Br4] (1) described previously as an intermediate product in the reaction of K2[OsBr6] with DMSO and characterized by EAS and ESR spectra. The coordination of DMSO molecules was established by IR and 1H and 13C NMR spectroscopy. The oxidation state of osmium and trans arrangement of DMSO molecules in the anion were established by ESR. The behavior of complex 1 in solutions was studied by EAS, ESR, and mass-spectrometry: a displacement of Br− ions accompanied by the reduction of osmium to oxidation state +2 occurs in DMSO, a solvation with displacement of DMSO molecules is observed at the first stage in water and methanol (rate constants 2.3 × 10−4 and 1.7 × 10−3 s−1, respectively), the sequential substitution of DMSO molecules and osmium oxidation to form [OsIVBr6]2− ions takes place in 4 mol/L HBr. More... »

PAGES

678-682

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023614070195

DOI

http://dx.doi.org/10.1134/s0036023614070195

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002950686


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Peoples' Friendship University of Russia", 
          "id": "https://www.grid.ac/institutes/grid.77642.30", 
          "name": [
            "Peoples\u2019 Friendship University of Russia, ul. Miklukho-Maklaya 6, 117198, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rudnitskaya", 
        "givenName": "O. V.", 
        "id": "sg:person.013042732644.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013042732644.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Peoples' Friendship University of Russia", 
          "id": "https://www.grid.ac/institutes/grid.77642.30", 
          "name": [
            "Peoples\u2019 Friendship University of Russia, ul. Miklukho-Maklaya 6, 117198, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kultyshkina", 
        "givenName": "E. K.", 
        "id": "sg:person.012722423223.39", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012722423223.39"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Peoples' Friendship University of Russia", 
          "id": "https://www.grid.ac/institutes/grid.77642.30", 
          "name": [
            "Peoples\u2019 Friendship University of Russia, ul. Miklukho-Maklaya 6, 117198, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dobrokhotova", 
        "givenName": "E. V.", 
        "id": "sg:person.07455306474.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07455306474.64"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 117907, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Efimov", 
        "givenName": "N. N.", 
        "id": "sg:person.01024204401.44", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01024204401.44"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 117907, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ugolkova", 
        "givenName": "E. A.", 
        "id": "sg:person.015265162315.78", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015265162315.78"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Peoples' Friendship University of Russia", 
          "id": "https://www.grid.ac/institutes/grid.77642.30", 
          "name": [
            "Peoples\u2019 Friendship University of Russia, ul. Miklukho-Maklaya 6, 117198, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ovcharov", 
        "givenName": "M. V.", 
        "id": "sg:person.0665105427.20", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0665105427.20"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 117907, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Minin", 
        "givenName": "V. V.", 
        "id": "sg:person.011207441575.56", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011207441575.56"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1107/s0108270189000843", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022563642"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr0307291", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053816661"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr0307291", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053816661"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic700405y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055581461"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic700405y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055581461"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1726439", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057792982"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2014-07", 
    "datePublishedReg": "2014-07-01", 
    "description": "The reaction of H2[OsBr6] with DMSO in ethanol solution resulted in DMSO complex [H(dmso-O)2][OsIII(dmso-S)2Br4] (1) described previously as an intermediate product in the reaction of K2[OsBr6] with DMSO and characterized by EAS and ESR spectra. The coordination of DMSO molecules was established by IR and 1H and 13C NMR spectroscopy. The oxidation state of osmium and trans arrangement of DMSO molecules in the anion were established by ESR. The behavior of complex 1 in solutions was studied by EAS, ESR, and mass-spectrometry: a displacement of Br\u2212 ions accompanied by the reduction of osmium to oxidation state +2 occurs in DMSO, a solvation with displacement of DMSO molecules is observed at the first stage in water and methanol (rate constants 2.3 \u00d7 10\u22124 and 1.7 \u00d7 10\u22123 s\u22121, respectively), the sequential substitution of DMSO molecules and osmium oxidation to form [OsIVBr6]2\u2212 ions takes place in 4 mol/L HBr.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0036023614070195", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1004031", 
        "issn": [
          "0036-0236", 
          "0044-457X"
        ], 
        "name": "Russian Journal of Inorganic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "7", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "59"
      }
    ], 
    "name": "Osmium dimethyl sulfoxide complexes: Synthesis and properties of [H(dmso)2][OsIII(dmso)2Br4]", 
    "pagination": "678-682", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "0e0d8eadb984d1f3d2ffe23b7b94fd98c8d545e2cdaa01c2b663daee5d8f44a0"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0036023614070195"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1002950686"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0036023614070195", 
      "https://app.dimensions.ai/details/publication/pub.1002950686"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T14:58", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8663_00000503.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S0036023614070195"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036023614070195'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036023614070195'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036023614070195'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036023614070195'


 

This table displays all metadata directly associated to this object as RDF triples.

118 TRIPLES      21 PREDICATES      31 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0036023614070195 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nb101c92fe0f94842b2616e50705781b5
4 schema:citation https://doi.org/10.1021/cr0307291
5 https://doi.org/10.1021/ic700405y
6 https://doi.org/10.1063/1.1726439
7 https://doi.org/10.1107/s0108270189000843
8 schema:datePublished 2014-07
9 schema:datePublishedReg 2014-07-01
10 schema:description The reaction of H2[OsBr6] with DMSO in ethanol solution resulted in DMSO complex [H(dmso-O)2][OsIII(dmso-S)2Br4] (1) described previously as an intermediate product in the reaction of K2[OsBr6] with DMSO and characterized by EAS and ESR spectra. The coordination of DMSO molecules was established by IR and 1H and 13C NMR spectroscopy. The oxidation state of osmium and trans arrangement of DMSO molecules in the anion were established by ESR. The behavior of complex 1 in solutions was studied by EAS, ESR, and mass-spectrometry: a displacement of Br− ions accompanied by the reduction of osmium to oxidation state +2 occurs in DMSO, a solvation with displacement of DMSO molecules is observed at the first stage in water and methanol (rate constants 2.3 × 10−4 and 1.7 × 10−3 s−1, respectively), the sequential substitution of DMSO molecules and osmium oxidation to form [OsIVBr6]2− ions takes place in 4 mol/L HBr.
11 schema:genre research_article
12 schema:inLanguage en
13 schema:isAccessibleForFree false
14 schema:isPartOf N695ef3fda6ce4e988b452da0b9f7736b
15 Nfd8a2f3901af4ec3bdb8387e17f92283
16 sg:journal.1004031
17 schema:name Osmium dimethyl sulfoxide complexes: Synthesis and properties of [H(dmso)2][OsIII(dmso)2Br4]
18 schema:pagination 678-682
19 schema:productId N1171586553eb4ae1a72676ab900db23d
20 N72a918869ee9459bbec1eff86bf82b7f
21 Nf459d73cb0904ed29c8753f0d6451507
22 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002950686
23 https://doi.org/10.1134/s0036023614070195
24 schema:sdDatePublished 2019-04-10T14:58
25 schema:sdLicense https://scigraph.springernature.com/explorer/license/
26 schema:sdPublisher Nf93b6a6ee6c24157b4dc85cb96fbf82f
27 schema:url http://link.springer.com/10.1134/S0036023614070195
28 sgo:license sg:explorer/license/
29 sgo:sdDataset articles
30 rdf:type schema:ScholarlyArticle
31 N1171586553eb4ae1a72676ab900db23d schema:name readcube_id
32 schema:value 0e0d8eadb984d1f3d2ffe23b7b94fd98c8d545e2cdaa01c2b663daee5d8f44a0
33 rdf:type schema:PropertyValue
34 N2175ca728cd847588d7f0987258ed079 rdf:first sg:person.015265162315.78
35 rdf:rest N2f930cbfe828414d8b0787b01e610311
36 N2f930cbfe828414d8b0787b01e610311 rdf:first sg:person.0665105427.20
37 rdf:rest N47afa6c5614d4ec68742b7f773ef5976
38 N47afa6c5614d4ec68742b7f773ef5976 rdf:first sg:person.011207441575.56
39 rdf:rest rdf:nil
40 N54289d60af414e0fb03727469f2e333b rdf:first sg:person.07455306474.64
41 rdf:rest Nbd74a99123894d46b8b507b33144ec7a
42 N695ef3fda6ce4e988b452da0b9f7736b schema:issueNumber 7
43 rdf:type schema:PublicationIssue
44 N72a918869ee9459bbec1eff86bf82b7f schema:name dimensions_id
45 schema:value pub.1002950686
46 rdf:type schema:PropertyValue
47 Nab3203957e6542cdb26a0ff26f0d068e rdf:first sg:person.012722423223.39
48 rdf:rest N54289d60af414e0fb03727469f2e333b
49 Nb101c92fe0f94842b2616e50705781b5 rdf:first sg:person.013042732644.49
50 rdf:rest Nab3203957e6542cdb26a0ff26f0d068e
51 Nbd74a99123894d46b8b507b33144ec7a rdf:first sg:person.01024204401.44
52 rdf:rest N2175ca728cd847588d7f0987258ed079
53 Nf459d73cb0904ed29c8753f0d6451507 schema:name doi
54 schema:value 10.1134/s0036023614070195
55 rdf:type schema:PropertyValue
56 Nf93b6a6ee6c24157b4dc85cb96fbf82f schema:name Springer Nature - SN SciGraph project
57 rdf:type schema:Organization
58 Nfd8a2f3901af4ec3bdb8387e17f92283 schema:volumeNumber 59
59 rdf:type schema:PublicationVolume
60 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
61 schema:name Chemical Sciences
62 rdf:type schema:DefinedTerm
63 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
64 schema:name Physical Chemistry (incl. Structural)
65 rdf:type schema:DefinedTerm
66 sg:journal.1004031 schema:issn 0036-0236
67 0044-457X
68 schema:name Russian Journal of Inorganic Chemistry
69 rdf:type schema:Periodical
70 sg:person.01024204401.44 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
71 schema:familyName Efimov
72 schema:givenName N. N.
73 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01024204401.44
74 rdf:type schema:Person
75 sg:person.011207441575.56 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
76 schema:familyName Minin
77 schema:givenName V. V.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011207441575.56
79 rdf:type schema:Person
80 sg:person.012722423223.39 schema:affiliation https://www.grid.ac/institutes/grid.77642.30
81 schema:familyName Kultyshkina
82 schema:givenName E. K.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012722423223.39
84 rdf:type schema:Person
85 sg:person.013042732644.49 schema:affiliation https://www.grid.ac/institutes/grid.77642.30
86 schema:familyName Rudnitskaya
87 schema:givenName O. V.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013042732644.49
89 rdf:type schema:Person
90 sg:person.015265162315.78 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
91 schema:familyName Ugolkova
92 schema:givenName E. A.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015265162315.78
94 rdf:type schema:Person
95 sg:person.0665105427.20 schema:affiliation https://www.grid.ac/institutes/grid.77642.30
96 schema:familyName Ovcharov
97 schema:givenName M. V.
98 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0665105427.20
99 rdf:type schema:Person
100 sg:person.07455306474.64 schema:affiliation https://www.grid.ac/institutes/grid.77642.30
101 schema:familyName Dobrokhotova
102 schema:givenName E. V.
103 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07455306474.64
104 rdf:type schema:Person
105 https://doi.org/10.1021/cr0307291 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053816661
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1021/ic700405y schema:sameAs https://app.dimensions.ai/details/publication/pub.1055581461
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1063/1.1726439 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057792982
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1107/s0108270189000843 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022563642
112 rdf:type schema:CreativeWork
113 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
114 schema:name Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 117907, Moscow, Russia
115 rdf:type schema:Organization
116 https://www.grid.ac/institutes/grid.77642.30 schema:alternateName Peoples' Friendship University of Russia
117 schema:name Peoples’ Friendship University of Russia, ul. Miklukho-Maklaya 6, 117198, Moscow, Russia
118 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...