Synthesis and chemical stability of (5,15-bis(2-thienyl)- and 5,15-diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetra-n-butyl-21H,23H-porphinato)copper(II) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-03

AUTHORS

M. E. Klyueva, A. A. Nikitin, T. N. Lomova, A. S. Semeikin

ABSTRACT

(5,15-Bis(2-thienyl)-and 5,15-diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetra-n-butyl-21H,23H-porphinato)copper(II) complexes were synthesized and the basicity, absorption spectra (UV-Vis, IR, 1H NMR) of the macrocyclic ligands and the stability of the complexes in AcOH-H2SO4 mixed solvents were studied with the aim to reveal the effect of 2-thienyl substituent on the properties of substituted porphyrins. Data on kinetics were obtained, reaction mechanism of complex dissociation was reasoned, and the effect of functional substitution on the properties of macrocyclic bases and their complexes with copper(II) were determined. More... »

PAGES

237-243

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023614030103

DOI

http://dx.doi.org/10.1134/s0036023614030103

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017923333


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