Ontology type: schema:ScholarlyArticle
2014-02
AUTHORSS. A. Novikov, E. V. Peresypkina, L. B. Serezhkina, A. V. Virovets, V. N. Serezhkin
ABSTRACT[[UO2(L)(OH)] (I), (CN3H6)2[(UO2)2CrO4(L)4] · 2H2O (II), and [UO2(H2O)5][(UO2)2Cr2O7(L)4] (III) crystals, where L is picolinate ion C5H4NCOO−, have been synthesized and studied by X-ray diffraction and IR spectroscopy. Complex I crystallizes in triclinic system with the unit cell parameters a = 6.2858(5) Å, b = 7.9522(5) Å, c = 8.3598(6) Å, α = 79.527(6)°, β = 87.760(6)°, γ = 79.126(6)°, space group P, Z = 2, R = 0.0306, and complexes II and III crystalize in monoclinic system with a = 8.8630(9) Å, b = 13.4540(13) Å, c = 31.266(3) Å, β = 93.118(3)°, space group C2/c, Z = 4, R = 0.0187 (II), and a = 7.3172(4) Å, b = 15.4719(8) Å, c = 16.6534(10) Å, β = 98.943(4)°, space group P21/m, Z = 2, R = 0.0588 (III). The structure of complex I is built of electronegative [UO2(L)(OH)] chains, which belong to the AT11M2 crystallochemical group (A = UO22+, T11 = L, M2 = OH−) of uranyl complexes. The structure of complexes II and III contains [(UO2)2(L′)(L)4]2− dimers (L′ = CrO42−or Cr2O72−), which belong to the A2B2B401 group (A = UO22+,B2 = L′, B01 = L). The specifics of intermolecular interactions in the structures of complexes I–III and some their analogues have been considered using molecular Voronoi-Dirichlet polyhedra. More... »
PAGES63-71
http://scigraph.springernature.com/pub.10.1134/s0036023614020168
DOIhttp://dx.doi.org/10.1134/s0036023614020168
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