Coordination compounds of neodymium, samarium, and europium with acyldihydrazones of imino-, oxo-, and thiodiacetic acids and 3-methyl-1-phenyl-4-formylpyrazol-5-one View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-04

AUTHORS

O. V. Konnik, Z. Z. Bekirova, V. F. Shul’gin, S. B. Meshkova, P. G. Doga, S. S. Smola, G. G. Aleksandrov, I. L. Eremenko

ABSTRACT

The coordination compounds of neodymium(III), samarium(III), and europium(III) with the acyldihydrazones of imino-, oxo-, and thiodiacetic acids and 3-methyl-1-phenyl-4-formylpyrazol-5-one were synthesized and studied. According to X-ray diffraction data, the complexes are binuclear and the lanthanide cations are linked by three binucleating ligands. The coordination polyhedra have a three-cap triangular prism geometry, the prism bases being formed by oxygen atoms and the vertices being occupied by the imine nitrogen atoms. Solid Nd(III) and Sm(III) complexes show intense luminescence in the spectral regions characteristic of these cations. Europium(III) complexes are liminescence-inactive due to the low efficiency of excitation energy transfer to the resonance levels of the central atom. More... »

PAGES

308-314

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023614020120

DOI

http://dx.doi.org/10.1134/s0036023614020120

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041194891


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