Composition and structure of rhenium(VI) complexes as found by EPR and laser mass spectrometry View Full Text


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Article Info

DATE

2013-08-08

AUTHORS

L. V. Borisova, A. S. Borodkov, A. A. Grechnikov, E. A. Ugolkova, V. V. Minin

ABSTRACT

Reactions of rhenium with oxymonothiophenols in ReO4−-HCl (H2SO4)-L systems (where L is 3-tert-butyl-2-mercaptophenol or 3-tert-butyl-2-mercapto-6-methylphenol) to form complexes, in which rhenium has an oxidation number of +6, have been studied by means of electron paramagnetic resonance (EPR), spectrophotometry, and surface-assisted laser desorption/ionization methods. The parameters of EPR spectra have been determined, and ion peaks in the mass spectra have been identified. It has been found that the studied complexes are octahedrons distorted in the equatorial plane and the composition of compounds satisfies the Re: L ratio of 1: 3. More... »

PAGES

940-944

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023613080044

DOI

http://dx.doi.org/10.1134/s0036023613080044

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034582696


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