Anionic lanthanide complexes with 3-methyl-4-formyl-1-phenyl-5-pyrazolone View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-06

AUTHORS

V. F. Shul’gin, S. V. Abkhairova, O. V. Konnik, S. B. Meshkova, Z. M. Topilova, E. B. Rusanov, G. G. Aleksandrov, I. L. Eremenko

ABSTRACT

The coordination compounds Na[LnL4] · 2H2O and [NBu4][LnL4] (Ln = Nd, Sm, Eu, Tb; HL is 3-methyl-4-formyl-1-phenyl-5-pyrazolone) have been synthesized and studied by IR spectroscopy and thermogravimetry. According to X-ray diffraction data, the coordination polyhedra of lanthanides are shaped as square antiprisms and formed by the oxygen atoms of four deprotonated moieties of the enol form of 4-formyl-5-pyrazolone. In the complex Na[EuL4] · 2H2O, sodium cations are bonded to the two nitrogen atoms of pyrazole heterocycles, combining discrete complex anions into two interpenetrating three-dimensional frameworks. Polycrystalline samples of neodymium(III), samarium(III), and terbium(III) complexes manifest intense luminescence in the spectral regions that are typical for them. More... »

PAGES

678-683

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023613060223

DOI

http://dx.doi.org/10.1134/s0036023613060223

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027792303


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