Synthesis and luminescent properties of neutral Eu(III) and Gd(III) complexes with 1-(1,5-dimethyl-1h-pyrazol-4-yl)-4,4,4-trifluoro-1,3-butanedione and 4,4,5,5,6,6,6-heptafluoro-1-(1-methyl-1H-pyrazol-4-yl)-1,3-hexanedione View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-04

AUTHORS

I. V. Taidakov, B. E. Zaitsev, A. N. Lobanov, A. G. Vitukhnovskii, N. P. Datskevich, A. S. Selyukov

ABSTRACT

Neutral [EuL3Phen] complexes were synthesized by the reaction of EuCl3 with heterocyclic diketones-1-(1,5-dimethyl-1H-pyrazol-4-yl)-4,4,4-trifluoro-1,3-butanedione and 4,4,5,5,6,6,6-heptafluoro-1-(1-methyl-1H-pyrazol-4-yl)-1,3-hexanedione—and 1,10-phenanthroline (Phen) in an aqueous alcohol solution in the presence of NaOH. The reaction of GdCl3 with the same diketones under analogous conditions, but without adding 1,10-phenanthroline, yielded [GdL3(H2O)2] complexes. The composition of the complexes was determined by elemental analysis, and their optical and luminescent properties were examined. More... »

PAGES

411-415

References to SciGraph publications

  • 2010-06. Photophysical properties of lanthanide complexes with 5-nitro-1,10-phenanthroline in MONATSHEFTE FÜR CHEMIE - CHEMICAL MONTHLY
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