Trends in formation of the nanocrystalline structure and cationic ordering in the Dy2O3-HfO2 (1: 1) system View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-03-14

AUTHORS

V. V. Popov, A. P. Menushenkov, Ya. V. Zubavichus, A. A. Veligzhanin, A. A. Yaroslavtsev, R. V. Chernikov, D. S. Leshchev, V. F. Petrunin, S. A. Korovin, J. Bednarcik

ABSTRACT

Evolution of the nanocrystalline structure of the complex oxide Dy2HfO5 in the course of thermal annealing at temperatures to 1600°C has been studied by a combination of X-ray and synchrotron methods, including traditional and anomalous X-ray diffraction, PDF, EXAFS, and SAXS. The changes in crystallite size upon annealing of the as-synthesized amorphous precursor have been analyzed in detail. The systematic distortions of a fluorite-type perfect crystal structure (space group \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$Fm\bar 3m$$\end{document}) related to the nonequivalence of the local environment of the Dy and Hf cations but not resulting in formation of a pyrochlore-type cationordered structure in this system have been examined. More... »

PAGES

331-337

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023613030121

DOI

http://dx.doi.org/10.1134/s0036023613030121

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036545704


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