Synthesis and structure of (CN3H6)2[UO2CrO4(C5H3N(COO)2)] View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-01

AUTHORS

L. B. Serezhkina, E. V. Peresypkina, S. A. Novikov, A. V. Virovets, V. N. Serezhkin

ABSTRACT

(CN3H6)2[UO2CrO4(C5H3N(COO)2)] crystals (where CN3H6 is the guanidinium cation and C5H3N(COO)2 is the pyridine-2,6-dicarboxylate anion) have been synthesized and studied by X-ray diffraction and IR spectroscopy. The compound crystallizes in triclinic system with the unit cell parameters a = 7.4115(3) Å, b = 10.0365(7) Å, c = 12.1822(10) Å, α = 93.992(6)°, β = 97.749(7)°, γ = 96.907(6)°; space group , Z = 2, R = 0.0721. The structure consists of [UO2CrO4(C5H3N(COO)2)]24−, centrosymmetric dimers linked with the outer-sphere guanidinium ions by means of electrostatic interactions and hydrogen bonds. [UO2CrO4(C5H3N(COO)2)]24− dimers belong to the AT001B2 crystallochemical group (A = UO22+, T001 = C5H3N(COO)22− B2 = CrO42−) of uranyl complexes. Using molecular Voronoi-Dirichlet polyhedra, we have established that, in addition to hydrogen bonds, the π-π stacking interaction also produces some effect on the packing of uranyl-containing complexes in the studied structure. More... »

PAGES

19-25

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023613010166

DOI

http://dx.doi.org/10.1134/s0036023613010166

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1029043075


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