Complexation of Co(II) with phosphonomethylaminosuccinic acid in solutions View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-11

AUTHORS

S. V. Volkov, E. K. Trunova, A. V. Shovkovaya, A. O. Gudima

ABSTRACT

Complexation in the Co(II)-phosphonomethylaminosuccinic acid (H4L) system in aqueous solutions at component ratios of 1 : 1 and 1 : 2 and cCo(II) = 1 × 10−2 mol/L was studied by electronic absorption spectroscopy. The formation of various protonated complexes of the general formula Co(HnL)m(OH)q (n = 3−0; m = 1–2; q = 0–2) was found, and their stability constants and distribution diagrams were calculated. It was demonstrated that the bis complexes have the structure of a distorted octahedron, and the octahedron → tetrahedron rearrangement of the coordination polyhedron occurs in the equimolar complexes at pH > 8. More... »

PAGES

1508-1512

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023612110150

DOI

http://dx.doi.org/10.1134/s0036023612110150

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1023236530


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Ukraine", 
          "id": "https://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. akademika Palladina 32/34, 252142, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Volkov", 
        "givenName": "S. V.", 
        "id": "sg:person.0777572327.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0777572327.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Ukraine", 
          "id": "https://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. akademika Palladina 32/34, 252142, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Trunova", 
        "givenName": "E. K.", 
        "id": "sg:person.010727141167.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010727141167.52"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Ukraine", 
          "id": "https://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. akademika Palladina 32/34, 252142, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shovkovaya", 
        "givenName": "A. V.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Ukraine", 
          "id": "https://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. akademika Palladina 32/34, 252142, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gudima", 
        "givenName": "A. O.", 
        "id": "sg:person.0771471501.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0771471501.55"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1080/00958979308035153", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010917328"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/a909207b", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015937224"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00958978508073900", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026301602"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1590/s0100-40422005000600019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044419429"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2012-11", 
    "datePublishedReg": "2012-11-01", 
    "description": "Complexation in the Co(II)-phosphonomethylaminosuccinic acid (H4L) system in aqueous solutions at component ratios of 1 : 1 and 1 : 2 and cCo(II) = 1 \u00d7 10\u22122 mol/L was studied by electronic absorption spectroscopy. The formation of various protonated complexes of the general formula Co(HnL)m(OH)q (n = 3\u22120; m = 1\u20132; q = 0\u20132) was found, and their stability constants and distribution diagrams were calculated. It was demonstrated that the bis complexes have the structure of a distorted octahedron, and the octahedron \u2192 tetrahedron rearrangement of the coordination polyhedron occurs in the equimolar complexes at pH > 8.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0036023612110150", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1004031", 
        "issn": [
          "0036-0236", 
          "0044-457X"
        ], 
        "name": "Russian Journal of Inorganic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "11", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "57"
      }
    ], 
    "name": "Complexation of Co(II) with phosphonomethylaminosuccinic acid in solutions", 
    "pagination": "1508-1512", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "6eb4465c7446797d688f8a2f51d97bab47562f6f1a7b98272dae9e3252dc2599"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0036023612110150"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1023236530"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0036023612110150", 
      "https://app.dimensions.ai/details/publication/pub.1023236530"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T15:49", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8664_00000505.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S0036023612110150"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036023612110150'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036023612110150'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036023612110150'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036023612110150'


 

This table displays all metadata directly associated to this object as RDF triples.

93 TRIPLES      21 PREDICATES      31 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0036023612110150 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N8658accd23db4da3ac434a26de7d84d0
4 schema:citation https://doi.org/10.1039/a909207b
5 https://doi.org/10.1080/00958978508073900
6 https://doi.org/10.1080/00958979308035153
7 https://doi.org/10.1590/s0100-40422005000600019
8 schema:datePublished 2012-11
9 schema:datePublishedReg 2012-11-01
10 schema:description Complexation in the Co(II)-phosphonomethylaminosuccinic acid (H4L) system in aqueous solutions at component ratios of 1 : 1 and 1 : 2 and cCo(II) = 1 × 10−2 mol/L was studied by electronic absorption spectroscopy. The formation of various protonated complexes of the general formula Co(HnL)m(OH)q (n = 3−0; m = 1–2; q = 0–2) was found, and their stability constants and distribution diagrams were calculated. It was demonstrated that the bis complexes have the structure of a distorted octahedron, and the octahedron → tetrahedron rearrangement of the coordination polyhedron occurs in the equimolar complexes at pH > 8.
11 schema:genre research_article
12 schema:inLanguage en
13 schema:isAccessibleForFree false
14 schema:isPartOf N36bb4c15e5644a62891f8067b5fdfe4b
15 Nae3dab8e55a4481d826b3003152c518b
16 sg:journal.1004031
17 schema:name Complexation of Co(II) with phosphonomethylaminosuccinic acid in solutions
18 schema:pagination 1508-1512
19 schema:productId N4eba7163ba2c44b4abfcd3edbf76feae
20 N6be9386c73a44f30963718ca92859b20
21 Nead5105f38604a50929c7f153a112d57
22 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023236530
23 https://doi.org/10.1134/s0036023612110150
24 schema:sdDatePublished 2019-04-10T15:49
25 schema:sdLicense https://scigraph.springernature.com/explorer/license/
26 schema:sdPublisher Nb4cf1ba56c2f4bc2bc8934e79f4ad7fc
27 schema:url http://link.springer.com/10.1134/S0036023612110150
28 sgo:license sg:explorer/license/
29 sgo:sdDataset articles
30 rdf:type schema:ScholarlyArticle
31 N0f3dfb14951c4e41ab437942d3e9f746 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
32 schema:familyName Shovkovaya
33 schema:givenName A. V.
34 rdf:type schema:Person
35 N10ea0965b1af443b84b77f8b36b4f256 rdf:first sg:person.0771471501.55
36 rdf:rest rdf:nil
37 N36bb4c15e5644a62891f8067b5fdfe4b schema:volumeNumber 57
38 rdf:type schema:PublicationVolume
39 N4eba7163ba2c44b4abfcd3edbf76feae schema:name doi
40 schema:value 10.1134/s0036023612110150
41 rdf:type schema:PropertyValue
42 N6be9386c73a44f30963718ca92859b20 schema:name dimensions_id
43 schema:value pub.1023236530
44 rdf:type schema:PropertyValue
45 N84e7715b18034cf2838a907d0c68dc6c rdf:first sg:person.010727141167.52
46 rdf:rest N892d01284f1342c0aa5b5fb850de00f4
47 N8658accd23db4da3ac434a26de7d84d0 rdf:first sg:person.0777572327.37
48 rdf:rest N84e7715b18034cf2838a907d0c68dc6c
49 N892d01284f1342c0aa5b5fb850de00f4 rdf:first N0f3dfb14951c4e41ab437942d3e9f746
50 rdf:rest N10ea0965b1af443b84b77f8b36b4f256
51 Nae3dab8e55a4481d826b3003152c518b schema:issueNumber 11
52 rdf:type schema:PublicationIssue
53 Nb4cf1ba56c2f4bc2bc8934e79f4ad7fc schema:name Springer Nature - SN SciGraph project
54 rdf:type schema:Organization
55 Nead5105f38604a50929c7f153a112d57 schema:name readcube_id
56 schema:value 6eb4465c7446797d688f8a2f51d97bab47562f6f1a7b98272dae9e3252dc2599
57 rdf:type schema:PropertyValue
58 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
59 schema:name Chemical Sciences
60 rdf:type schema:DefinedTerm
61 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
62 schema:name Inorganic Chemistry
63 rdf:type schema:DefinedTerm
64 sg:journal.1004031 schema:issn 0036-0236
65 0044-457X
66 schema:name Russian Journal of Inorganic Chemistry
67 rdf:type schema:Periodical
68 sg:person.010727141167.52 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
69 schema:familyName Trunova
70 schema:givenName E. K.
71 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010727141167.52
72 rdf:type schema:Person
73 sg:person.0771471501.55 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
74 schema:familyName Gudima
75 schema:givenName A. O.
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0771471501.55
77 rdf:type schema:Person
78 sg:person.0777572327.37 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
79 schema:familyName Volkov
80 schema:givenName S. V.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0777572327.37
82 rdf:type schema:Person
83 https://doi.org/10.1039/a909207b schema:sameAs https://app.dimensions.ai/details/publication/pub.1015937224
84 rdf:type schema:CreativeWork
85 https://doi.org/10.1080/00958978508073900 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026301602
86 rdf:type schema:CreativeWork
87 https://doi.org/10.1080/00958979308035153 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010917328
88 rdf:type schema:CreativeWork
89 https://doi.org/10.1590/s0100-40422005000600019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044419429
90 rdf:type schema:CreativeWork
91 https://www.grid.ac/institutes/grid.418751.e schema:alternateName National Academy of Sciences of Ukraine
92 schema:name Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. akademika Palladina 32/34, 252142, Kiev, Ukraine
93 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...