Magnetic properties of spacer-armed dinuclear copper(II) complexes View Full Text


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Article Info

DATE

2012-04

AUTHORS

V. F. Shul’gin, O. V. Konnik, A. S. Bogomyakov, V. I. Ovcharenko, V. V. Minin

ABSTRACT

The results of static magnetic susceptibility studies of spacer-armed dinuclear copper(II) complexes with dicarboxylic acid acylhydrazones are described. Weak exchange coupling between paramagnetic centers has been detected with an exchange parameter value of −2J ∼ 1–7 cm−1. Short intermolecular contacts give rise to additional weak antiferromagnetic exchange coupling between copper cations comparable in terms of energy with superexchange inside the dinuclear complex (−zJ′ ∼ 0.6–5.0 cm−1). More... »

PAGES

552-556

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023612040225

DOI

http://dx.doi.org/10.1134/s0036023612040225

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009643577


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