Synthesis, structure, and luminescent properties of lanthanide coordination compounds with 3-methyl-4-formyl-1-phenylpyrazol-5-one View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-03

AUTHORS

V. F. Shul’gin, S. V. Abkhairova, O. V. Konnik, S. B. Meshkova, Z. M. Topilova, M. A. Kiskin, I. L. Eremenko

ABSTRACT

An exchange reaction of the sodium salt of 3-methyl-1-phenyl-4-formylpyrazol-5-one (HL) with chlorides or nitrates of lanthanides (Ln = La, Nd, Sm, Eu, Gd, Tb, Dy, and Yb) was used to synthesize coordination compounds of composition LnL3·nSolv (Solv = H2O or EtOH). According to powder X-ray diffraction data, these compounds constitute two series: one comprises lanthanum and neodymium complexes, and the other, samarium, europium, gadolinium, terbium, dysprosium, and ytterbium complexes. For the complexes of the first series, the structure was solved in a single-crystal diffraction experiment carried out on [La2(μ-L)3(L)3(H2O)3]·2MeOH. The lanthanum atoms in the complex are at a distance of 4.222(2) — from each other, and they are structurally nonequivalent and linked by three 5-hydroxy-4-formylpyrazole anions. Solid-phase samples of the coordination compounds under study feature weak luminescence in the spectral regions intrinsic to lanthanide cations. More... »

PAGES

420-426

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023612030291

DOI

http://dx.doi.org/10.1134/s0036023612030291

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