Synthesis, structure, and luminescent properties of lanthanide coordination compounds with 3-methyl-4-formyl-1-phenylpyrazol-5-one View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-03

AUTHORS

V. F. Shul’gin, S. V. Abkhairova, O. V. Konnik, S. B. Meshkova, Z. M. Topilova, M. A. Kiskin, I. L. Eremenko

ABSTRACT

An exchange reaction of the sodium salt of 3-methyl-1-phenyl-4-formylpyrazol-5-one (HL) with chlorides or nitrates of lanthanides (Ln = La, Nd, Sm, Eu, Gd, Tb, Dy, and Yb) was used to synthesize coordination compounds of composition LnL3·nSolv (Solv = H2O or EtOH). According to powder X-ray diffraction data, these compounds constitute two series: one comprises lanthanum and neodymium complexes, and the other, samarium, europium, gadolinium, terbium, dysprosium, and ytterbium complexes. For the complexes of the first series, the structure was solved in a single-crystal diffraction experiment carried out on [La2(μ-L)3(L)3(H2O)3]·2MeOH. The lanthanum atoms in the complex are at a distance of 4.222(2) — from each other, and they are structurally nonequivalent and linked by three 5-hydroxy-4-formylpyrazole anions. Solid-phase samples of the coordination compounds under study feature weak luminescence in the spectral regions intrinsic to lanthanide cations. More... »

PAGES

420-426

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023612030291

DOI

http://dx.doi.org/10.1134/s0036023612030291

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034040444


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "name": [
            "Taurian National V.I. Vernadsky University, Simferopol, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shul\u2019gin", 
        "givenName": "V. F.", 
        "id": "sg:person.0616602656.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0616602656.25"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Taurian National V.I. Vernadsky University, Simferopol, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Abkhairova", 
        "givenName": "S. V.", 
        "id": "sg:person.016351366151.07", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016351366151.07"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Sevastopol Scientific and Production Center for Standardization, Metrology, and Certification, Sevastopol, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Konnik", 
        "givenName": "O. V.", 
        "id": "sg:person.01045006120.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01045006120.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Ukraine", 
          "id": "https://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Bogatsky Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Meshkova", 
        "givenName": "S. B.", 
        "id": "sg:person.0664716056.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664716056.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Ukraine", 
          "id": "https://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Bogatsky Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Topilova", 
        "givenName": "Z. M.", 
        "id": "sg:person.0647442720.15", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0647442720.15"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 13, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kiskin", 
        "givenName": "M. A.", 
        "id": "sg:person.01172445335.81", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01172445335.81"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 13, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Eremenko", 
        "givenName": "I. L.", 
        "id": "sg:person.0745631435.08", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0745631435.08"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/j.ica.2004.06.024", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004548830"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b406082m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023069865"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b406082m", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023069865"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0022-2313(98)00013-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028503428"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1631-0748(02)01449-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034546630"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s1631-0748(02)01449-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034546630"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ccr.2005.03.013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043425967"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr0401063", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1054042023"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr0401063", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1054042023"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm035392y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055410453"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cm035392y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055410453"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2012-03", 
    "datePublishedReg": "2012-03-01", 
    "description": "An exchange reaction of the sodium salt of 3-methyl-1-phenyl-4-formylpyrazol-5-one (HL) with chlorides or nitrates of lanthanides (Ln = La, Nd, Sm, Eu, Gd, Tb, Dy, and Yb) was used to synthesize coordination compounds of composition LnL3\u00b7nSolv (Solv = H2O or EtOH). According to powder X-ray diffraction data, these compounds constitute two series: one comprises lanthanum and neodymium complexes, and the other, samarium, europium, gadolinium, terbium, dysprosium, and ytterbium complexes. For the complexes of the first series, the structure was solved in a single-crystal diffraction experiment carried out on [La2(\u03bc-L)3(L)3(H2O)3]\u00b72MeOH. The lanthanum atoms in the complex are at a distance of 4.222(2) \u2014 from each other, and they are structurally nonequivalent and linked by three 5-hydroxy-4-formylpyrazole anions. Solid-phase samples of the coordination compounds under study feature weak luminescence in the spectral regions intrinsic to lanthanide cations.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0036023612030291", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1004031", 
        "issn": [
          "0036-0236", 
          "0044-457X"
        ], 
        "name": "Russian Journal of Inorganic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "57"
      }
    ], 
    "name": "Synthesis, structure, and luminescent properties of lanthanide coordination compounds with 3-methyl-4-formyl-1-phenylpyrazol-5-one", 
    "pagination": "420-426", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "a22900f2d3ee74270f171eafaec51821c5243bfc68f45de7a0e1aa5ae6c23a3f"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0036023612030291"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1034040444"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0036023612030291", 
      "https://app.dimensions.ai/details/publication/pub.1034040444"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T13:14", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8659_00000506.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S0036023612030291"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036023612030291'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036023612030291'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036023612030291'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036023612030291'


 

This table displays all metadata directly associated to this object as RDF triples.

133 TRIPLES      21 PREDICATES      34 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0036023612030291 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N9198d45fadcf429b838a0a5f2cc9d9c9
4 schema:citation https://doi.org/10.1016/j.ccr.2005.03.013
5 https://doi.org/10.1016/j.ica.2004.06.024
6 https://doi.org/10.1016/s0022-2313(98)00013-1
7 https://doi.org/10.1016/s1631-0748(02)01449-2
8 https://doi.org/10.1021/cm035392y
9 https://doi.org/10.1021/cr0401063
10 https://doi.org/10.1039/b406082m
11 schema:datePublished 2012-03
12 schema:datePublishedReg 2012-03-01
13 schema:description An exchange reaction of the sodium salt of 3-methyl-1-phenyl-4-formylpyrazol-5-one (HL) with chlorides or nitrates of lanthanides (Ln = La, Nd, Sm, Eu, Gd, Tb, Dy, and Yb) was used to synthesize coordination compounds of composition LnL3·nSolv (Solv = H2O or EtOH). According to powder X-ray diffraction data, these compounds constitute two series: one comprises lanthanum and neodymium complexes, and the other, samarium, europium, gadolinium, terbium, dysprosium, and ytterbium complexes. For the complexes of the first series, the structure was solved in a single-crystal diffraction experiment carried out on [La2(μ-L)3(L)3(H2O)3]·2MeOH. The lanthanum atoms in the complex are at a distance of 4.222(2) — from each other, and they are structurally nonequivalent and linked by three 5-hydroxy-4-formylpyrazole anions. Solid-phase samples of the coordination compounds under study feature weak luminescence in the spectral regions intrinsic to lanthanide cations.
14 schema:genre research_article
15 schema:inLanguage en
16 schema:isAccessibleForFree false
17 schema:isPartOf N0cf7181a3a794574ba5f269eabff688d
18 N5412ceb29bcd48199599e7f91608ab99
19 sg:journal.1004031
20 schema:name Synthesis, structure, and luminescent properties of lanthanide coordination compounds with 3-methyl-4-formyl-1-phenylpyrazol-5-one
21 schema:pagination 420-426
22 schema:productId N1e70b6c22e39465f971987a6cf351a06
23 N45795ce8702c4efd911caca16f3542da
24 Ncba3a6c2df984b26ae37e41db54afe14
25 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034040444
26 https://doi.org/10.1134/s0036023612030291
27 schema:sdDatePublished 2019-04-10T13:14
28 schema:sdLicense https://scigraph.springernature.com/explorer/license/
29 schema:sdPublisher N14197d1ee0084055bd0de209a3cfd4dd
30 schema:url http://link.springer.com/10.1134/S0036023612030291
31 sgo:license sg:explorer/license/
32 sgo:sdDataset articles
33 rdf:type schema:ScholarlyArticle
34 N0cf7181a3a794574ba5f269eabff688d schema:volumeNumber 57
35 rdf:type schema:PublicationVolume
36 N0d1bba18cfd84ba48feedc3e35981901 rdf:first sg:person.016351366151.07
37 rdf:rest N78342b9120cb48b197fd76d9ae99d25d
38 N14197d1ee0084055bd0de209a3cfd4dd schema:name Springer Nature - SN SciGraph project
39 rdf:type schema:Organization
40 N14ce883b2e6a492984f126660e43c5f1 schema:name Taurian National V.I. Vernadsky University, Simferopol, Ukraine
41 rdf:type schema:Organization
42 N1e1b6613006247deb455016d1ada3704 rdf:first sg:person.01172445335.81
43 rdf:rest N696cf9e893474d1fada05bc9e1161509
44 N1e70b6c22e39465f971987a6cf351a06 schema:name readcube_id
45 schema:value a22900f2d3ee74270f171eafaec51821c5243bfc68f45de7a0e1aa5ae6c23a3f
46 rdf:type schema:PropertyValue
47 N1f1264e55f9b4e90acd978f1a89cef19 schema:name Taurian National V.I. Vernadsky University, Simferopol, Ukraine
48 rdf:type schema:Organization
49 N45795ce8702c4efd911caca16f3542da schema:name doi
50 schema:value 10.1134/s0036023612030291
51 rdf:type schema:PropertyValue
52 N5412ceb29bcd48199599e7f91608ab99 schema:issueNumber 3
53 rdf:type schema:PublicationIssue
54 N696cf9e893474d1fada05bc9e1161509 rdf:first sg:person.0745631435.08
55 rdf:rest rdf:nil
56 N78342b9120cb48b197fd76d9ae99d25d rdf:first sg:person.01045006120.37
57 rdf:rest Nd83d27c16f7a43d6b7ffe9757749e60b
58 N9198d45fadcf429b838a0a5f2cc9d9c9 rdf:first sg:person.0616602656.25
59 rdf:rest N0d1bba18cfd84ba48feedc3e35981901
60 Nb0dcea37bab3446295bdb3ea1c6eda46 schema:name Sevastopol Scientific and Production Center for Standardization, Metrology, and Certification, Sevastopol, Ukraine
61 rdf:type schema:Organization
62 Nb577663ab89c4092a1b19455cd5b0832 rdf:first sg:person.0647442720.15
63 rdf:rest N1e1b6613006247deb455016d1ada3704
64 Ncba3a6c2df984b26ae37e41db54afe14 schema:name dimensions_id
65 schema:value pub.1034040444
66 rdf:type schema:PropertyValue
67 Nd83d27c16f7a43d6b7ffe9757749e60b rdf:first sg:person.0664716056.01
68 rdf:rest Nb577663ab89c4092a1b19455cd5b0832
69 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
70 schema:name Chemical Sciences
71 rdf:type schema:DefinedTerm
72 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
73 schema:name Inorganic Chemistry
74 rdf:type schema:DefinedTerm
75 sg:journal.1004031 schema:issn 0036-0236
76 0044-457X
77 schema:name Russian Journal of Inorganic Chemistry
78 rdf:type schema:Periodical
79 sg:person.01045006120.37 schema:affiliation Nb0dcea37bab3446295bdb3ea1c6eda46
80 schema:familyName Konnik
81 schema:givenName O. V.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01045006120.37
83 rdf:type schema:Person
84 sg:person.01172445335.81 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
85 schema:familyName Kiskin
86 schema:givenName M. A.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01172445335.81
88 rdf:type schema:Person
89 sg:person.016351366151.07 schema:affiliation N1f1264e55f9b4e90acd978f1a89cef19
90 schema:familyName Abkhairova
91 schema:givenName S. V.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016351366151.07
93 rdf:type schema:Person
94 sg:person.0616602656.25 schema:affiliation N14ce883b2e6a492984f126660e43c5f1
95 schema:familyName Shul’gin
96 schema:givenName V. F.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0616602656.25
98 rdf:type schema:Person
99 sg:person.0647442720.15 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
100 schema:familyName Topilova
101 schema:givenName Z. M.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0647442720.15
103 rdf:type schema:Person
104 sg:person.0664716056.01 schema:affiliation https://www.grid.ac/institutes/grid.418751.e
105 schema:familyName Meshkova
106 schema:givenName S. B.
107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664716056.01
108 rdf:type schema:Person
109 sg:person.0745631435.08 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
110 schema:familyName Eremenko
111 schema:givenName I. L.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0745631435.08
113 rdf:type schema:Person
114 https://doi.org/10.1016/j.ccr.2005.03.013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043425967
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1016/j.ica.2004.06.024 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004548830
117 rdf:type schema:CreativeWork
118 https://doi.org/10.1016/s0022-2313(98)00013-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028503428
119 rdf:type schema:CreativeWork
120 https://doi.org/10.1016/s1631-0748(02)01449-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034546630
121 rdf:type schema:CreativeWork
122 https://doi.org/10.1021/cm035392y schema:sameAs https://app.dimensions.ai/details/publication/pub.1055410453
123 rdf:type schema:CreativeWork
124 https://doi.org/10.1021/cr0401063 schema:sameAs https://app.dimensions.ai/details/publication/pub.1054042023
125 rdf:type schema:CreativeWork
126 https://doi.org/10.1039/b406082m schema:sameAs https://app.dimensions.ai/details/publication/pub.1023069865
127 rdf:type schema:CreativeWork
128 https://www.grid.ac/institutes/grid.418751.e schema:alternateName National Academy of Sciences of Ukraine
129 schema:name Bogatsky Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
130 rdf:type schema:Organization
131 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
132 schema:name Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 13, 119991, Moscow, Russia
133 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...