Synthesis and study of (CN3H6)2[(UO2)2(C2O4)(SeO3)2] by IR spectroscopy and X-ray diffraction View Full Text


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Article Info

DATE

2012-02

AUTHORS

D. V. Pushkin, E. V. Peresypkina, L. B. Serezhkina, A. V. Savchenkov, A. V. Virovets, V. N. Serezhkin

ABSTRACT

Single crystals of (CN3H6)2[(UO2)2(C2O4)(SeO3)2] were synthesized and studied by IR spectroscopy and X-ray diffraction. The compound crystallizes in the triclinic system with the unit cell parameters a = 7.1169(12) Å, b = 7.4874(10) Å, c = 8.9748(14) Å, α = 88.243(6)°, β = 74.546(6)°, γ = 81.445(6)°, space group , Z = 1, R = 0.0304. The main structural units of the crystals are layers of the [(UO2)2(C2O4)(SeO3)2]2− composition; the layers belong to the crystal chemical group A2K02T23 (A = UO22+K02 = C2O42−, T3 = SeO3–) of uranyl complexes. Uranium-containing complex groups are linked by electrostatic interactions and a network of hydrogen bonds with CN3H6+ guanidinium ions to form a three-dimensional framework. More... »

PAGES

175-180

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023612020210

DOI

http://dx.doi.org/10.1134/s0036023612020210

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1021876692


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