Crystal and molecular structure of diphenyliodonium triiodide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-02

AUTHORS

M. S. Chernov’yants, I. V. Burykin, Z. A. Starikova, A. A. Rostovskaya

ABSTRACT

A new salt diphenyliodonium triiodide (C12H10I4) was obtained. The [C12H10I+][I3−] compound was isolated as red brown crystals and studied by single-crystal X-ray diffraction. The structure of diphenyliodonium triiodide consists of separate, virtually linear I3− anions and C12H10I+ cations. Strong intermolecular anion-anion (I3−…I3−) and anion-cation (I3−…I+) interactions in the crystal structure leads to a change in the symmetry of triiodide ions. The complex formation in the system organic cation iodide-elementary iodine was studied by spectrophotometry. The complex composition was found (1: 1), and the stability constant of the complex in chloroform was determined (loggB = 3.91). More... »

PAGES

193-196

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023612020064

DOI

http://dx.doi.org/10.1134/s0036023612020064

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018675900


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Southern Federal University", 
          "id": "https://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Southern Federal University, ul. Bolshaya Sadovaya 105/42, 344006, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chernov\u2019yants", 
        "givenName": "M. S.", 
        "id": "sg:person.01000402427.43", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01000402427.43"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University", 
          "id": "https://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Southern Federal University, ul. Bolshaya Sadovaya 105/42, 344006, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Burykin", 
        "givenName": "I. V.", 
        "id": "sg:person.01046515627.36", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01046515627.36"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Starikova", 
        "givenName": "Z. A.", 
        "id": "sg:person.014473641160.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University", 
          "id": "https://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Southern Federal University, ul. Bolshaya Sadovaya 105/42, 344006, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rostovskaya", 
        "givenName": "A. A.", 
        "id": "sg:person.010033426661.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010033426661.37"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1021/cr800332c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037097038"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr800332c", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037097038"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr940424+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053813650"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr940424+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053813650"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo030022e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056018213"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo030022e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056018213"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2012-02", 
    "datePublishedReg": "2012-02-01", 
    "description": "A new salt diphenyliodonium triiodide (C12H10I4) was obtained. The [C12H10I+][I3\u2212] compound was isolated as red brown crystals and studied by single-crystal X-ray diffraction. The structure of diphenyliodonium triiodide consists of separate, virtually linear I3\u2212 anions and C12H10I+ cations. Strong intermolecular anion-anion (I3\u2212\u2026I3\u2212) and anion-cation (I3\u2212\u2026I+) interactions in the crystal structure leads to a change in the symmetry of triiodide ions. The complex formation in the system organic cation iodide-elementary iodine was studied by spectrophotometry. The complex composition was found (1: 1), and the stability constant of the complex in chloroform was determined (loggB = 3.91).", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s0036023612020064", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1004031", 
        "issn": [
          "0036-0236", 
          "0044-457X"
        ], 
        "name": "Russian Journal of Inorganic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "57"
      }
    ], 
    "name": "Crystal and molecular structure of diphenyliodonium triiodide", 
    "pagination": "193-196", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "58fba38a4e4e98744815b1a58e234583c7e093136f5725ea9ea344f9b0c34253"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s0036023612020064"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1018675900"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s0036023612020064", 
      "https://app.dimensions.ai/details/publication/pub.1018675900"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T19:55", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8681_00000504.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S0036023612020064"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s0036023612020064'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s0036023612020064'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s0036023612020064'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s0036023612020064'


 

This table displays all metadata directly associated to this object as RDF triples.

94 TRIPLES      21 PREDICATES      30 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s0036023612020064 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N0645c9cdbe9448b1856d3a4b7ed3ea81
4 schema:citation https://doi.org/10.1021/cr800332c
5 https://doi.org/10.1021/cr940424+
6 https://doi.org/10.1021/jo030022e
7 schema:datePublished 2012-02
8 schema:datePublishedReg 2012-02-01
9 schema:description A new salt diphenyliodonium triiodide (C12H10I4) was obtained. The [C12H10I+][I3−] compound was isolated as red brown crystals and studied by single-crystal X-ray diffraction. The structure of diphenyliodonium triiodide consists of separate, virtually linear I3− anions and C12H10I+ cations. Strong intermolecular anion-anion (I3−…I3−) and anion-cation (I3−…I+) interactions in the crystal structure leads to a change in the symmetry of triiodide ions. The complex formation in the system organic cation iodide-elementary iodine was studied by spectrophotometry. The complex composition was found (1: 1), and the stability constant of the complex in chloroform was determined (loggB = 3.91).
10 schema:genre research_article
11 schema:inLanguage en
12 schema:isAccessibleForFree false
13 schema:isPartOf N553cad7ea91441b7bc5896a987972593
14 Ne3004bcd9aa44004bcf2008db84cbffd
15 sg:journal.1004031
16 schema:name Crystal and molecular structure of diphenyliodonium triiodide
17 schema:pagination 193-196
18 schema:productId N40b8a42e85b2439da151d71ed03a116b
19 N9a50012e3ccd44eaa1aede6f39ece33c
20 Nc15a4502b678406d8180a11d2650425b
21 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018675900
22 https://doi.org/10.1134/s0036023612020064
23 schema:sdDatePublished 2019-04-10T19:55
24 schema:sdLicense https://scigraph.springernature.com/explorer/license/
25 schema:sdPublisher Nfd3b9a7d0f934a7ba56b2aec5b79f098
26 schema:url http://link.springer.com/10.1134/S0036023612020064
27 sgo:license sg:explorer/license/
28 sgo:sdDataset articles
29 rdf:type schema:ScholarlyArticle
30 N0645c9cdbe9448b1856d3a4b7ed3ea81 rdf:first sg:person.01000402427.43
31 rdf:rest N0ce495666f5d4e7e8929f17e4abd4697
32 N0ce495666f5d4e7e8929f17e4abd4697 rdf:first sg:person.01046515627.36
33 rdf:rest Na5fe51498dc44518b62afc7f230a6061
34 N40b8a42e85b2439da151d71ed03a116b schema:name dimensions_id
35 schema:value pub.1018675900
36 rdf:type schema:PropertyValue
37 N553cad7ea91441b7bc5896a987972593 schema:issueNumber 2
38 rdf:type schema:PublicationIssue
39 N9a50012e3ccd44eaa1aede6f39ece33c schema:name doi
40 schema:value 10.1134/s0036023612020064
41 rdf:type schema:PropertyValue
42 Na5fe51498dc44518b62afc7f230a6061 rdf:first sg:person.014473641160.05
43 rdf:rest Nf77aeea1c03840d2906ccee6e7b154c1
44 Nc15a4502b678406d8180a11d2650425b schema:name readcube_id
45 schema:value 58fba38a4e4e98744815b1a58e234583c7e093136f5725ea9ea344f9b0c34253
46 rdf:type schema:PropertyValue
47 Ne3004bcd9aa44004bcf2008db84cbffd schema:volumeNumber 57
48 rdf:type schema:PublicationVolume
49 Nf77aeea1c03840d2906ccee6e7b154c1 rdf:first sg:person.010033426661.37
50 rdf:rest rdf:nil
51 Nfd3b9a7d0f934a7ba56b2aec5b79f098 schema:name Springer Nature - SN SciGraph project
52 rdf:type schema:Organization
53 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
54 schema:name Chemical Sciences
55 rdf:type schema:DefinedTerm
56 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
57 schema:name Physical Chemistry (incl. Structural)
58 rdf:type schema:DefinedTerm
59 sg:journal.1004031 schema:issn 0036-0236
60 0044-457X
61 schema:name Russian Journal of Inorganic Chemistry
62 rdf:type schema:Periodical
63 sg:person.01000402427.43 schema:affiliation https://www.grid.ac/institutes/grid.182798.d
64 schema:familyName Chernov’yants
65 schema:givenName M. S.
66 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01000402427.43
67 rdf:type schema:Person
68 sg:person.010033426661.37 schema:affiliation https://www.grid.ac/institutes/grid.182798.d
69 schema:familyName Rostovskaya
70 schema:givenName A. A.
71 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010033426661.37
72 rdf:type schema:Person
73 sg:person.01046515627.36 schema:affiliation https://www.grid.ac/institutes/grid.182798.d
74 schema:familyName Burykin
75 schema:givenName I. V.
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01046515627.36
77 rdf:type schema:Person
78 sg:person.014473641160.05 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
79 schema:familyName Starikova
80 schema:givenName Z. A.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05
82 rdf:type schema:Person
83 https://doi.org/10.1021/cr800332c schema:sameAs https://app.dimensions.ai/details/publication/pub.1037097038
84 rdf:type schema:CreativeWork
85 https://doi.org/10.1021/cr940424+ schema:sameAs https://app.dimensions.ai/details/publication/pub.1053813650
86 rdf:type schema:CreativeWork
87 https://doi.org/10.1021/jo030022e schema:sameAs https://app.dimensions.ai/details/publication/pub.1056018213
88 rdf:type schema:CreativeWork
89 https://www.grid.ac/institutes/grid.182798.d schema:alternateName Southern Federal University
90 schema:name Southern Federal University, ul. Bolshaya Sadovaya 105/42, 344006, Rostov-on-Don, Russia
91 rdf:type schema:Organization
92 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
93 schema:name Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia
94 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...