Reaction of copper(II) cysteinate with thiosemicarbazide: Crystal structure of a complex of copper(II) thiocyanate with thiosemicarbazide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-02

AUTHORS

A. S. Antsyshkina, G. G. Sadikov, T. V. Koksharova, V. S. Sergienko, D. A. Golub

ABSTRACT

The reaction of copper(II) cysteinate with thiosemicarbazide (TSC) in water was found to yield complex of copper(II) thiocyanate of the [Cu(TSC)2(SCN)2] composition, whose crystal structure was determined by X-ray crystallography. Crystals of the complex are triclinic with a = 6.040 Å, b = 7.112 Å, c = 8.276 Å, α = 91.34°, β = 101.72°, Γ = 114.83°, Z = 2, space group . Structural units of the complex are [Cu(TSC)2]2+ centrosymmetric cations and (SCN)− anions linked by hydrogen bonds (HB), as well as by electrostatic and π-π stacking interactions. The coordination polyhedron of Cu atoms is a square completed to bipyramid; the bonds Cu(1)-N(3), Cu(1)-S(1), and Cu(1)-S(2) are 2.002 Å, 2.303 Å, and 3.015 Å, respectively. More... »

PAGES

169-174

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023612020027

DOI

http://dx.doi.org/10.1134/s0036023612020027

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1007169463


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