Synthesis and crystal structure of [UO2CrO4(C5NH5COO)] · H2O View Full Text


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Article Info

DATE

2012-01

AUTHORS

L. B. Serezhkina, E. V. Peresypkina, S. A. Novikov, A. V. Virovets, V. N. Serezhkin

ABSTRACT

Synthesis and X-ray diffraction study of [UO2CrO4(C5NH5COO)] · H2O crystals were performed. The compound crystallizes in the monoclinic system with the unit cell parameters a = 7.5025(3) Å, b = 11.5188(6) Å, c = 13.0518(6) Å, β = 97.877(4)°, V = 1117.29(9) Å3, space group P21/n, Z = 4, R = 0.0263. The structure is formed by three [UO2CrO4(C5NH5COO)] layers parallel to (10). The coordination polyhedron of uranium atoms is a pentagonal bipyramid, whose apices are occupied by oxygen atoms of uranyl, three chromate groups, and two molecules of isonicotinic acid. Crystal chemical formula of the [UO2CrO4(C5NH5COO)] layer can be represented as AT3B2, where A = UO22+, T3 = CrO42−, and B2 = C5NH5COO molecules. The isonicotinic acid molecules are in the form of zwitterions. More... »

PAGES

41-45

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023612010202

DOI

http://dx.doi.org/10.1134/s0036023612010202

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032340764


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