Inclusion compounds of cucurbit[n]urils with metal complexes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-12

AUTHORS

O. A. Gerasko, V. P. Fedin

ABSTRACT

A new class of supramolecular compounds—inclusion compounds of metal complexes encapsulated in organic macrocyclic cavitands cucurbit[n]urils (CB[n], C6nH6nN4nO2n, n = 7−10)—has been surveyed. A unique combination of a rather rigid hydrophobic intramolecular cavity and negatively charged portals favors the formation of stable host-guest compounds. Basic methods of synthesis of inclusion compounds of CB[n] with metal complexes have been reported, and the structures of the resulting products isolated as crystals and characterized by X-ray crystallography have been considered. The effect of encapsulation on the geometric and spectral characteristics of the complexes and their redox properties has been traced. It has been shown that encapsulation in CB[n] can lead to a change in the reactivity of the complexes in thermolysis and isomerization and aquation reactions. Encapsulation of biologically active metal complexes in CB[n] is a promising strategy for designing new-generation prolonged-action pharmaceuticals. More... »

PAGES

2025-2046

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s003602361113002x

DOI

http://dx.doi.org/10.1134/s003602361113002x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040517295


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