Copper(II) complex with salicylaldehyde N-(2-salicylideneiminoglutaryl)hydrazone: Synthesis and structure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-11

AUTHORS

A. N. Gusev, E. A. Zamnius, V. F. Shul’gin, O. V. Konnik, I. L. Eremenko, G. G. Aleksandrov, V. V. Minin

ABSTRACT

A copper(II) complex with salicylaldehyde N-(2-salicylideneiminoglutaryl)hydrazone (H4L) of the formula [Cu2L · 2Py]2 · 8H2O (I) was obtained and characterized by X-ray diffraction. The crystals are monoclinic, space group P21, a = 13.0663 Å, b = 16.5553 Å, c = 17.7650 Å, β = 97.9420°; Z = 4. The complex is tetranuclear with a “dimer-of-dimers” structure in which the copper cations of two binuclear subunits are linked by phenoxy bridges. The EPR spectra of solutions of complex I show a superposition of two signals of four HFS lines (g1 = 2.111, a1 = 56.8 × 10−4 cm−1 and g2 = 2.183, a2 = 71.0 × 10−4 cm−1). More... »

PAGES

1729-1732

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s003602361111009x

DOI

http://dx.doi.org/10.1134/s003602361111009x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047098304


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