Spacer-armed binuclear copper(ii) complexes with salicylidene hydrazones of N-benzoylaminodicarboxylic acids View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-10

AUTHORS

V. F. Shul’gin, E. A. Zamnius, A. N. Gusev, O. V. Konnik, E. B. Rusanov, V. Ya. Zub, V. V. Minin

ABSTRACT

The structure and EPR spectra of copper(II) complexes with bis(salicylidene)hydrozones of N-benzoyl-L-aspartic and N-benzoyl-L-glutamic acids have been described. The compounds have been studied by chemical and thermal analyses, IR spectroscopy, and EPR spectroscopy. The molecular and crystal structure of the copper(II) complex with bis(salicylidene)hydrozone of N-benzoyl-L-aspartic acid (H4L) of composition [Cu2L · 2Py] · 2CH3OH · H2O has been determined by X-ray single-crystal diffraction. The crystals are monoclinic: a = 10.3316(7) Å, b = 16.7552(9) Å,c = 11.0137(6) Å, β = 105.758(3)°, space group P21, Z = 2. The complex has a polymeric structure composed of alternating copper-containing binuclear fragments bound to each other either via phenoxy bridges or via an aliphatic spacer (the Cu…Cu distances are 3.471 Å and 8.939 Å, respectively). The EPR spectra of the solutions of the complexes under study shows an isotropic signal comprising seven HFS lines due to two equivalent copper nuclei with the spin Hamiltonian parameters g = 2.115–2.122 and aCu = (36.1–36.9) × 10−4 cm−1, which indicates the reaization of weak exchange coupling of the paramagnetic centers. More... »

PAGES

1598

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023611100226

DOI

http://dx.doi.org/10.1134/s0036023611100226

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1007921917


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