Crystal and molecular structures of triaquabis(5-nitro-2-acetamidobenzoato)copper(II) dihydrate View Full Text


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Article Info

DATE

2011-09

AUTHORS

A. T. Mamedova, K. A. Lysenko, V. S. Sergienko, E. M. Movsumov

ABSTRACT

A new copper(II) complex [Cu(5-NO2-2-CH3CONHC6H3COO)2(H2O)3] · 2H2O was synthesized by the reaction of sodium 5-nitro-5-acetamidobenzoate with CuSO4 · 5H2O (2: 1), and its structure was determined by X-ray diffraction. Crystals are monoclinic: a = 11.7146(7) Å, b = 16.8463(10) Å, c = 13.2408(9) Å, β = 113.896(5)°, Z = 4, ρcalc = 1.668 g/cm3, space group P21/c, R = 0.0338. In the monomer complex, the copper atom has an elongated square-pyramidal coordination (4 + 1); the coordination sphere is formed by two oxygen atoms of the carboxylate groups of two monodentate organic ligands and the three oxygen atoms O(w) of the water molecules (the O(3w) atom is in the axial position). In the structure, the complex molecules are linked by hydrogen bonds involving two uncoordinated water molecules. More... »

PAGES

1380

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023611090166

DOI

http://dx.doi.org/10.1134/s0036023611090166

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034321336


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