Synthesis of finely disperse nickel particles by thermolysis of complex (N2H5)[Ni(NH2NHCOO)3] · H2O in organic liquids and refinement of crystal ... View Full Text


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Article Info

DATE

2011-06

AUTHORS

R. K. Tukhtaev, S. V. Larionov, R. F. Klevtsova, L. I. Myachina, L. A. Glinskaya, T. A. Udalova, N. Z. Lyakhov

ABSTRACT

The crystal structure of the complex (N2H5)[Ni(NH2NHCOO)3] · H2O (I) was refined using X-ray diffraction data (obtained on an Apex X8 diffractometer, MoKα radiation, 1830 Fhkl, R = 0.0182). The structure is built of complex anions [Ni(NH2NHCOO)3]−, cations N2H5+, and water molecules and is characterized by strong hydrogen bonds N-H…O, O-H…O, and N-H…N. The N3O3 coordination polyhedron around a Ni atom is a slightly distorted octahedron. The thermal decomposition of complex I was studied in high-boiling organic liquids. The feasibility of preparing non-pyrophoric nickel powders having particle sizes of up to 20 nm is shown. More... »

PAGES

881-887

References to SciGraph publications

  • 1985-10. Preparation, characterization and thermal analysis of metal hydrazinocarboxylate derivatives in PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES. SECTION A
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    http://scigraph.springernature.com/pub.10.1134/s0036023611060234

    DOI

    http://dx.doi.org/10.1134/s0036023611060234

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