Binuclear copper(II) complexes with acyldihydrazones of benzenedicarboxylic acids with pyrrolidine or piperidine View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-06

AUTHORS

V. F. Shul’gin, Yu. V. Trush, O. V. Konnik, E. B. Rusanov, V. Ya. Zub, V. V. Minin

ABSTRACT

The adducts of binuclear copper(II) complexes with acyldihydrazones formed by 1,3- or 1,4-benzenedicarboxylic acid and some nitrogen-containing Lewis bases (pyrrolidine, piperidine) were synthesized and studied. The structure of copper(II) complex with bis(salicylidene)hydrazone of terephthalic acid (H4L), [Cu2L(Pirr)4] · CH3OH, was determined by X-ray diffraction data. The crystals are monoclinic: a = 15.5142(7) Å, b = 13.8784(6) Å, c = 17.8873(8) Å; β = 91.990(2)°, space group C2/c, Z = 4. The number of symmetrically independent reflections was 4269, R = 0.0303, Rw = 0.0827. The complex contains two equivalent copper atoms located at a 11.021 Å is a tetragonal pyramid. EPR spectral features of the adducts were studied. More... »

PAGES

861-867

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s0036023611050238

DOI

http://dx.doi.org/10.1134/s0036023611050238

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000605100


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